1RU
Bonds
First atom | Second atom | Bond order type | Distance (experimental model) | Distance (ideal model) | Properties |
C8 | C7 | sing | 1.53Å | 1.53Å | |
C7 | C1 | sing | 1.51Å | 1.52Å | |
C7 | O9 | sing | 1.43Å | 1.44Å | |
CL2 | C2 | sing | 1.74Å | 1.72Å | |
C1 | C2 | doub | 1.38Å | 1.39Å | Aromatic |
C1 | C3 | sing | 1.38Å | 1.40Å | Aromatic |
O9 | C13 | sing | 1.36Å | 1.38Å | |
C2 | C4 | sing | 1.38Å | 1.39Å | Aromatic |
CL1 | C3 | sing | 1.74Å | 1.72Å | |
C3 | C5 | doub | 1.39Å | 1.38Å | Aromatic |
C4 | C6 | doub | 1.38Å | 1.39Å | Aromatic |
C5 | C6 | sing | 1.38Å | 1.39Å | Aromatic |
C5 | F12 | sing | 1.35Å | 1.33Å | |
C13 | C18 | doub | 1.39Å | 1.40Å | Aromatic |
C13 | C14 | sing | 1.39Å | 1.40Å | Aromatic |
O19 | C18 | sing | 1.34Å | 1.23Å | Aromatic |
O19 | C20 | sing | 1.35Å | 1.23Å | Aromatic |
N22 | C14 | sing | 1.39Å | 1.41Å | |
C18 | C17 | sing | 1.41Å | 1.38Å | Aromatic |
C14 | N15 | doub | 1.33Å | 1.40Å | Aromatic |
C20 | C21 | doub | 1.35Å | 1.38Å | Aromatic |
C17 | C21 | sing | 1.47Å | 1.36Å | Aromatic |
C17 | C16 | doub | 1.39Å | 1.37Å | Aromatic |
N15 | C16 | sing | 1.32Å | 1.39Å | Aromatic |
C21 | C23 | sing | 1.49Å | 1.50Å | |
C23 | C24 | sing | 1.41Å | 1.37Å | Aromatic |
C23 | C27 | doub | 1.36Å | 1.38Å | Aromatic |
C24 | N25 | doub | 1.31Å | 1.35Å | Aromatic |
C27 | N26 | sing | 1.35Å | 1.35Å | Aromatic |
N25 | N26 | sing | 1.40Å | 1.27Å | Aromatic |
N26 | C28 | sing | 1.47Å | 1.48Å | |
C28 | C29 | sing | 1.53Å | 1.55Å | |
C28 | C33 | sing | 1.53Å | 1.54Å | |
C29 | C30 | sing | 1.53Å | 1.53Å | |
C33 | C32 | sing | 1.53Å | 1.54Å | |
C30 | N31 | sing | 1.47Å | 1.47Å | |
C32 | N31 | sing | 1.47Å | 1.47Å | |
C6 | H1 | sing | 1.08Å | 1.08Å | |
C4 | H2 | sing | 1.08Å | 1.08Å | |
C7 | H3 | sing | 1.09Å | 1.10Å | |
C8 | H4 | sing | 1.09Å | 1.10Å | |
C8 | H5 | sing | 1.09Å | 1.10Å | |
C8 | H6 | sing | 1.09Å | 1.10Å | |
C20 | H7 | sing | 1.08Å | 1.08Å | |
C16 | H8 | sing | 1.08Å | 1.08Å | |
N22 | H9 | sing | 0.97Å | 1.00Å | |
N22 | H10 | sing | 0.97Å | 1.00Å | |
C27 | H11 | sing | 1.08Å | 1.08Å | |
C24 | H12 | sing | 1.08Å | 1.08Å | |
C28 | H13 | sing | 1.09Å | 1.10Å | |
C33 | H14 | sing | 1.09Å | 1.10Å | |
C33 | H15 | sing | 1.09Å | 1.10Å | |
C32 | H16 | sing | 1.09Å | 1.10Å | |
C32 | H17 | sing | 1.09Å | 1.10Å | |
N31 | H18 | sing | 1.01Å | 1.00Å | |
C30 | H20 | sing | 1.09Å | 1.10Å | |
C30 | H21 | sing | 1.09Å | 1.10Å | |
C29 | H22 | sing | 1.09Å | 1.10Å | |
C29 | H23 | sing | 1.09Å | 1.10Å |
Angles
First atom | Second atom | Third atom | Angle (experimental model) | Angle (ideal model) |
C8 | C7 | C1 | 108.1° | 109.5° |
C8 | C7 | O9 | 110.8° | 109.5° |
C8 | C7 | H3 | 108.3° | 109.5° |
C7 | C8 | H4 | 109.5° | 109.5° |
C7 | C8 | H5 | 109.5° | 109.5° |
C7 | C8 | H6 | 109.5° | 109.4° |
C1 | C7 | O9 | 111.7° | 109.5° |
C7 | C1 | C2 | 120.8° | 119.9° |
C7 | C1 | C3 | 120.5° | 120.0° |
C1 | C7 | H3 | 108.4° | 109.5° |
C7 | O9 | C13 | 126.9° | 117.0° |
O9 | C7 | H3 | 109.5° | 109.4° |
CL2 | C2 | C1 | 120.8° | 120.0° |
CL2 | C2 | C4 | 118.7° | 120.0° |
C2 | C1 | C3 | 118.7° | 120.0° |
C1 | C2 | C4 | 120.5° | 120.0° |
C1 | C3 | CL1 | 121.8° | 120.0° |
C1 | C3 | C5 | 120.8° | 120.0° |
O9 | C13 | C18 | 124.1° | 120.6° |
O9 | C13 | C14 | 119.0° | 120.5° |
C2 | C4 | C6 | 120.1° | 120.1° |
C2 | C4 | H2 | 119.9° | 119.9° |
CL1 | C3 | C5 | 117.4° | 120.0° |
C3 | C5 | C6 | 120.1° | 120.0° |
C3 | C5 | F12 | 119.1° | 120.0° |
C4 | C6 | C5 | 119.8° | 120.0° |
C4 | C6 | H1 | 120.1° | 120.0° |
C6 | C4 | H2 | 119.9° | 120.0° |
C6 | C5 | F12 | 120.8° | 120.0° |
C5 | C6 | H1 | 120.1° | 120.0° |
C18 | C13 | C14 | 117.0° | 118.9° |
C13 | C18 | O19 | 128.8° | 134.4° |
C13 | C18 | C17 | 121.4° | 118.0° |
C13 | C14 | N22 | 120.4° | 119.4° |
C13 | C14 | N15 | 120.8° | 121.2° |
C18 | O19 | C20 | 111.0° | 111.1° |
O19 | C18 | C17 | 109.8° | 107.6° |
O19 | C20 | C21 | 111.4° | 110.0° |
O19 | C20 | H7 | 124.3° | 125.0° |
N22 | C14 | N15 | 118.8° | 119.4° |
C14 | N22 | H9 | 109.5° | 120.0° |
C14 | N22 | H10 | 109.4° | 120.0° |
C18 | C17 | C21 | 105.4° | 105.4° |
C18 | C17 | C16 | 122.0° | 119.6° |
C14 | N15 | C16 | 121.2° | 122.1° |
C20 | C21 | C17 | 102.3° | 106.0° |
C20 | C21 | C23 | 127.3° | 127.0° |
C21 | C20 | H7 | 124.3° | 125.1° |
C21 | C17 | C16 | 132.6° | 135.1° |
C17 | C21 | C23 | 130.3° | 127.0° |
C17 | C16 | N15 | 117.6° | 120.3° |
C17 | C16 | H8 | 121.2° | 119.8° |
N15 | C16 | H8 | 121.2° | 119.9° |
C21 | C23 | C24 | 125.3° | 126.2° |
C21 | C23 | C27 | 130.3° | 126.2° |
C24 | C23 | C27 | 104.4° | 107.6° |
C23 | C24 | N25 | 108.9° | 108.1° |
C23 | C24 | H12 | 125.6° | 125.9° |
C23 | C27 | N26 | 107.4° | 107.6° |
C23 | C27 | H11 | 126.3° | 126.2° |
C24 | N25 | N26 | 108.7° | 108.5° |
N25 | C24 | H12 | 125.6° | 125.9° |
C27 | N26 | N25 | 110.6° | 108.2° |
C27 | N26 | C28 | 125.5° | 125.9° |
N26 | C27 | H11 | 126.3° | 126.2° |
N25 | N26 | C28 | 123.9° | 125.9° |
N26 | C28 | C29 | 110.4° | 109.5° |
N26 | C28 | C33 | 110.9° | 109.5° |
N26 | C28 | H13 | 109.3° | 109.5° |
C29 | C28 | C33 | 109.1° | 109.2° |
C28 | C29 | C30 | 111.9° | 109.3° |
C29 | C28 | H13 | 108.5° | 109.5° |
C28 | C29 | H22 | 108.9° | 109.5° |
C28 | C29 | H23 | 108.9° | 109.5° |
C28 | C33 | C32 | 111.6° | 109.3° |
C33 | C28 | H13 | 108.6° | 109.6° |
C28 | C33 | H14 | 108.9° | 109.5° |
C28 | C33 | H15 | 108.9° | 109.5° |
C29 | C30 | N31 | 110.1° | 109.5° |
C29 | C30 | H20 | 109.3° | 109.4° |
C29 | C30 | H21 | 109.3° | 109.5° |
C30 | C29 | H22 | 108.9° | 109.4° |
C30 | C29 | H23 | 108.9° | 109.5° |
C33 | C32 | N31 | 111.0° | 109.5° |
C32 | C33 | H14 | 108.9° | 109.5° |
C32 | C33 | H15 | 108.9° | 109.5° |
C33 | C32 | H16 | 109.1° | 109.5° |
C33 | C32 | H17 | 109.1° | 109.5° |
C30 | N31 | C32 | 113.8° | 111.2° |
C30 | N31 | H18 | 108.4° | 110.9° |
N31 | C30 | H20 | 109.3° | 109.4° |
N31 | C30 | H21 | 109.3° | 109.5° |
N31 | C32 | H16 | 109.1° | 109.4° |
N31 | C32 | H17 | 109.1° | 109.5° |
C32 | N31 | H18 | 108.4° | 111.0° |
H4 | C8 | H5 | 109.5° | 109.5° |
H4 | C8 | H6 | 109.5° | 109.4° |
H5 | C8 | H6 | 109.4° | 109.5° |
H9 | N22 | H10 | 109.5° | 120.0° |
H14 | C33 | H15 | 109.4° | 109.6° |
H16 | C32 | H17 | 109.5° | 109.4° |
H20 | C30 | H21 | 109.5° | 109.5° |
H22 | C29 | H23 | 109.5° | 109.5° |
Dihedrals
First atom | Second atom | Third atom | Fourth atom | Torsion (experimental model) | Torsion (ideal model) |
C8 | C7 | C1 | O9 | 122.1° | 120.0° |
C8 | C7 | C1 | H3 | 117.2° | 120.0° |
C8 | C7 | O9 | H3 | 119.4° | 119.9° |
C8 | C7 | C1 | C2 | 103.6° | 105.0° |
C8 | C7 | C1 | C3 | 75.3° | 74.8° |
C8 | C7 | O9 | C13 | 165.8° | 90.0° |
C7 | C8 | H4 | H5 | 120.0° | 120.1° |
C7 | C8 | H4 | H6 | 120.0° | 119.9° |
C7 | C8 | H5 | H6 | 120.0° | 120.0° |
C1 | C7 | O9 | H3 | 120.0° | 120.0° |
C7 | C1 | C2 | CL2 | 0.8° | 0.0° |
C7 | C1 | C2 | C3 | 178.9° | 179.8° |
C1 | C7 | O9 | C13 | 73.7° | 150.0° |
C7 | C1 | C2 | C4 | 179.6° | 180.0° |
C7 | C1 | C3 | CL1 | 1.0° | 0.3° |
C7 | C1 | C3 | C5 | 179.3° | 179.7° |
C1 | C7 | C8 | H4 | 180.0° | 179.9° |
C1 | C7 | C8 | H5 | 60.0° | 60.0° |
C1 | C7 | C8 | H6 | 60.0° | 60.0° |
O9 | C7 | C1 | C2 | 134.3° | 135.0° |
O9 | C7 | C1 | C3 | 46.8° | 45.2° |
C7 | O9 | C13 | C18 | 8.9° | 90.0° |
C7 | O9 | C13 | C14 | 171.2° | 90.3° |
O9 | C7 | C8 | H4 | 57.3° | 59.9° |
O9 | C7 | C8 | H5 | 177.4° | 180.0° |
O9 | C7 | C8 | H6 | 62.7° | 60.0° |
CL2 | C2 | C1 | C4 | 179.6° | 180.0° |
CL2 | C2 | C1 | C3 | 179.7° | 179.7° |
CL2 | C2 | C4 | C6 | 179.8° | 180.0° |
CL2 | C2 | C4 | H2 | 0.2° | 0.0° |
C2 | C1 | C3 | CL1 | 179.9° | 180.0° |
C2 | C1 | C3 | C5 | 0.4° | 0.5° |
C1 | C2 | C4 | C6 | 0.6° | 0.0° |
C1 | C2 | C4 | H2 | 179.4° | 179.9° |
C2 | C1 | C7 | H3 | 13.6° | 15.0° |
C3 | C1 | C2 | C4 | 0.8° | 0.2° |
C1 | C3 | CL1 | C5 | 179.8° | 179.5° |
C1 | C3 | C5 | C6 | 0.2° | 0.5° |
C1 | C3 | C5 | F12 | 180.0° | 179.7° |
C3 | C1 | C7 | H3 | 167.6° | 165.2° |
O9 | C13 | C18 | C14 | 179.9° | 179.7° |
O9 | C13 | C18 | O19 | 0.1° | 0.1° |
O9 | C13 | C14 | N22 | 0.2° | 0.0° |
O9 | C13 | C18 | C17 | 179.9° | 180.0° |
O9 | C13 | C14 | N15 | 179.9° | 179.8° |
C13 | O9 | C7 | H3 | 46.4° | 30.0° |
C2 | C4 | C6 | H2 | 180.0° | 180.0° |
C2 | C4 | C6 | C5 | 0.0° | 0.1° |
C2 | C4 | C6 | H1 | 180.0° | 180.0° |
CL1 | C3 | C5 | C6 | 179.6° | 180.0° |
CL1 | C3 | C5 | F12 | 0.2° | 0.2° |
C3 | C5 | C6 | C4 | 0.3° | 0.2° |
C3 | C5 | C6 | F12 | 179.9° | 179.8° |
C3 | C5 | C6 | H1 | 179.6° | 179.8° |
C4 | C6 | C5 | H1 | 180.0° | 180.0° |
C4 | C6 | C5 | F12 | 179.8° | 179.9° |
C5 | C6 | C4 | H2 | 179.9° | 179.9° |
F12 | C5 | C6 | H1 | 0.2° | 0.1° |
C13 | C18 | O19 | C17 | 179.8° | 179.9° |
C13 | C18 | O19 | C20 | 178.8° | 179.9° |
C18 | C13 | C14 | N22 | 179.9° | 179.7° |
C18 | C13 | C14 | N15 | 0.0° | 0.5° |
C13 | C18 | C17 | C21 | 179.6° | 179.9° |
C13 | C18 | C17 | C16 | 0.1° | 0.0° |
C14 | C13 | C18 | O19 | 179.8° | 179.8° |
C13 | C14 | N22 | N15 | 179.9° | 179.8° |
C14 | C13 | C18 | C17 | 0.0° | 0.3° |
C13 | C14 | N15 | C16 | 0.0° | 0.5° |
C13 | C14 | N22 | H9 | 179.9° | 0.1° |
C13 | C14 | N22 | H10 | 60.1° | 180.0° |
C18 | O19 | C20 | C21 | 2.2° | 0.0° |
O19 | C18 | C17 | C21 | 0.6° | 0.0° |
O19 | C18 | C17 | C16 | 179.9° | 180.0° |
C18 | O19 | C20 | H7 | 177.8° | 180.0° |
C20 | O19 | C18 | C17 | 1.0° | 0.0° |
O19 | C20 | C21 | H7 | 180.0° | 180.0° |
O19 | C20 | C21 | C17 | 2.4° | 0.0° |
O19 | C20 | C21 | C23 | 176.1° | 180.0° |
N22 | C14 | N15 | C16 | 179.9° | 179.7° |
C14 | N22 | H9 | H10 | 120.0° | 179.9° |
C18 | C17 | C21 | C20 | 1.7° | 0.0° |
C18 | C17 | C21 | C16 | 179.4° | 180.0° |
C18 | C17 | C16 | N15 | 0.1° | 0.0° |
C18 | C17 | C21 | C23 | 176.8° | 180.0° |
C18 | C17 | C16 | H8 | 179.8° | 180.0° |
C14 | N15 | C16 | C17 | 0.1° | 0.3° |
C14 | N15 | C16 | H8 | 179.9° | 179.8° |
N15 | C14 | N22 | H9 | 0.0° | 179.9° |
N15 | C14 | N22 | H10 | 120.0° | 0.2° |
C20 | C21 | C17 | C23 | 178.5° | 180.0° |
C20 | C21 | C17 | C16 | 178.9° | 180.0° |
C20 | C21 | C23 | C24 | 14.8° | 130.0° |
C20 | C21 | C23 | C27 | 164.8° | 49.7° |
C21 | C17 | C16 | N15 | 179.4° | 179.9° |
C17 | C21 | C23 | C24 | 167.1° | 50.0° |
C17 | C21 | C23 | C27 | 13.4° | 130.3° |
C17 | C21 | C20 | H7 | 177.6° | 180.0° |
C21 | C17 | C16 | H8 | 0.6° | 0.0° |
C17 | C16 | N15 | H8 | 180.0° | 179.9° |
C16 | C17 | C21 | C23 | 2.6° | 0.0° |
C21 | C23 | C24 | C27 | 179.6° | 179.7° |
C21 | C23 | C24 | N25 | 179.6° | 179.8° |
C21 | C23 | C27 | N26 | 179.9° | 180.0° |
C23 | C21 | C20 | H7 | 3.9° | 0.0° |
C21 | C23 | C27 | H11 | 0.1° | 0.0° |
C21 | C23 | C24 | H12 | 0.4° | 0.0° |
C23 | C24 | N25 | H12 | 180.0° | 179.8° |
C24 | C23 | C27 | N26 | 0.3° | 0.3° |
C23 | C24 | N25 | N26 | 0.3° | 0.5° |
C24 | C23 | C27 | H11 | 179.7° | 179.7° |
C27 | C23 | C24 | N25 | 0.0° | 0.4° |
C23 | C27 | N26 | H11 | 180.0° | 180.0° |
C23 | C27 | N26 | N25 | 0.5° | 0.0° |
C23 | C27 | N26 | C28 | 180.0° | 180.0° |
C27 | C23 | C24 | H12 | 180.0° | 179.8° |
C24 | N25 | N26 | C27 | 0.5° | 0.3° |
C24 | N25 | N26 | C28 | 179.9° | 179.7° |
C27 | N26 | N25 | C28 | 179.5° | 180.0° |
C27 | N26 | C28 | C29 | 139.7° | 85.0° |
C27 | N26 | C28 | C33 | 99.2° | 34.7° |
C27 | N26 | C28 | H13 | 20.5° | 154.9° |
N25 | N26 | C28 | C29 | 40.8° | 95.0° |
N25 | N26 | C28 | C33 | 80.3° | 145.3° |
N25 | N26 | C27 | H11 | 179.5° | 180.0° |
N26 | N25 | C24 | H12 | 179.7° | 179.8° |
N25 | N26 | C28 | H13 | 160.0° | 25.1° |
N26 | C28 | C29 | C33 | 122.2° | 119.9° |
N26 | C28 | C29 | H13 | 119.7° | 120.1° |
N26 | C28 | C33 | H13 | 120.1° | 120.1° |
N26 | C28 | C29 | C30 | 176.6° | 177.5° |
N26 | C28 | C33 | C32 | 175.2° | 177.6° |
C28 | N26 | C27 | H11 | 0.0° | 0.0° |
N26 | C28 | C33 | H14 | 64.5° | 62.5° |
N26 | C28 | C33 | H15 | 54.8° | 57.6° |
N26 | C28 | C29 | H22 | 56.2° | 57.7° |
N26 | C28 | C29 | H23 | 63.0° | 62.5° |
C29 | C28 | C33 | H13 | 118.1° | 120.0° |
C28 | C29 | C30 | H22 | 120.4° | 119.9° |
C28 | C29 | C30 | H23 | 120.4° | 120.0° |
C29 | C28 | C33 | C32 | 53.3° | 57.7° |
C28 | C29 | C30 | N31 | 55.9° | 59.1° |
C29 | C28 | C33 | H14 | 173.7° | 177.6° |
C29 | C28 | C33 | H15 | 67.0° | 62.3° |
C28 | C29 | C30 | H20 | 176.0° | 60.8° |
C28 | C29 | C30 | H21 | 64.2° | 179.2° |
C28 | C29 | H22 | H23 | 118.9° | 120.2° |
C33 | C28 | C29 | C30 | 54.4° | 57.6° |
C28 | C33 | C32 | H14 | 120.3° | 119.9° |
C28 | C33 | C32 | H15 | 120.3° | 120.0° |
C28 | C33 | C32 | N31 | 54.5° | 59.2° |
C28 | C33 | H14 | H15 | 119.0° | 120.1° |
C28 | C33 | C32 | H16 | 65.8° | 60.8° |
C28 | C33 | C32 | H17 | 174.7° | 179.2° |
C33 | C28 | C29 | H22 | 65.9° | 62.2° |
C33 | C28 | C29 | H23 | 174.8° | 177.6° |
C29 | C30 | N31 | H20 | 120.1° | 119.9° |
C29 | C30 | N31 | H21 | 120.1° | 120.1° |
C29 | C30 | N31 | C32 | 57.2° | 61.7° |
C30 | C29 | C28 | H13 | 63.7° | 62.4° |
C29 | C30 | N31 | H18 | 63.5° | 62.4° |
C29 | C30 | H20 | H21 | 119.7° | 120.0° |
C30 | C29 | H22 | H23 | 118.9° | 120.1° |
C33 | C32 | N31 | C30 | 56.7° | 61.7° |
C33 | C32 | N31 | H16 | 120.2° | 120.0° |
C33 | C32 | N31 | H17 | 120.2° | 120.1° |
C32 | C33 | C28 | H13 | 64.7° | 62.3° |
C32 | C33 | H14 | H15 | 119.0° | 120.1° |
C33 | C32 | H16 | H17 | 119.3° | 120.0° |
C33 | C32 | N31 | H18 | 63.9° | 62.3° |
C30 | N31 | C32 | H18 | 120.7° | 124.0° |
C30 | N31 | C32 | H16 | 63.5° | 58.3° |
C30 | N31 | C32 | H17 | 177.0° | 178.2° |
N31 | C30 | H20 | H21 | 119.7° | 120.0° |
N31 | C30 | C29 | H22 | 64.5° | 60.8° |
N31 | C30 | C29 | H23 | 176.3° | 179.1° |
N31 | C32 | C33 | H14 | 174.8° | 179.1° |
N31 | C32 | C33 | H15 | 65.9° | 60.8° |
N31 | C32 | H16 | H17 | 119.3° | 120.0° |
C32 | N31 | C30 | H20 | 177.3° | 58.3° |
C32 | N31 | C30 | H21 | 62.9° | 178.3° |
H1 | C6 | C4 | H2 | 0.0° | 0.1° |
H3 | C7 | C8 | H4 | 62.8° | 60.0° |
H3 | C7 | C8 | H5 | 57.2° | 60.1° |
H3 | C7 | C8 | H6 | 177.2° | 179.9° |
H4 | C8 | H5 | H6 | 120.0° | 120.0° |
H13 | C28 | C33 | H14 | 55.6° | 57.6° |
H13 | C28 | C33 | H15 | 174.9° | 177.8° |
H13 | C28 | C29 | H22 | 176.0° | 177.8° |
H13 | C28 | C29 | H23 | 56.7° | 57.6° |
H14 | C33 | C32 | H16 | 54.6° | 59.1° |
H14 | C33 | C32 | H17 | 64.9° | 60.9° |
H15 | C33 | C32 | H16 | 173.9° | 179.2° |
H15 | C33 | C32 | H17 | 54.4° | 59.3° |
H16 | C32 | N31 | H18 | 175.8° | 177.7° |
H17 | C32 | N31 | H18 | 56.3° | 57.7° |
H18 | N31 | C30 | H20 | 56.6° | 177.7° |
H18 | N31 | C30 | H21 | 176.4° | 57.7° |
H20 | C30 | C29 | H22 | 55.6° | 179.2° |
H20 | C30 | C29 | H23 | 63.6° | 59.2° |
H21 | C30 | C29 | H22 | 175.5° | 59.3° |
H21 | C30 | C29 | H23 | 56.2° | 60.8° |