7QPW

X-ray structure of the adduct obtained upon reaction of [cis-Rh2(OCOCH3)2(OCOCF3)2] with RNase A (1)

This is a non-PDB format compatible entry.

Summary for 7QPW

• Entry DOI: 10.2210/pdb7qpw/pdb
• Descriptor: Ribonuclease pancreatic, cis-bis(mi2-acetato-O, O')-(mi2-trifluoroacetato-O, O')-diaquo-dirhodium (II), (mi2-acetato-O, O')-hexaaquo-dirhodium (II), ... (5 entities in total)
• Functional Keywords: protein metalation, dirhodium tetraacetate derivative, hydrolase, dimetallic paddlewheel complexes
• Biological source: Bos taurus (cattle)
• Total number of polymer chains: 2
• Total formula weight: 28652.46

Authors

Loreto, D.,Merlino, A. (deposition date: 2022-01-05, release date: 2022-03-16, Last modification date: 2024-01-31)

• Primary citation: Loreto, D.,Esposito, A.,Demitri, N.,Guaragna, A.,Merlino, A.; Reactivity of a fluorine-containing dirhodium tetracarboxylate compound with proteins.; Dalton Trans, 51:3695-3705, 2022; PubMed: 35166290; DOI: 10.1039/d2dt00082b

Experimental method

X-RAY DIFFRACTION (1.15 Å)