4WHQ

Alkylperoxo reaction intermediate trapped in Protocatechuate 3,4-dioxygenase (pseudomonas putida) at pH 6.5

Summary for 4WHQ

Entry DOI	10.2210/pdb4whq/pdb
Related	4WHO 4WHP 4WHR 4WHS
Descriptor	Protocatechuate 3,4-dioxygenase alpha chain, GLYCEROL, (6S)-4-fluoro-6-hydroperoxy-6-hydroxycyclohexa-2,4-dien-1-one, ... (12 entities in total)
Functional Keywords	dioxygen activation, non-heme iron, intradiol dioxygenase, aromatic ring cleavage, catalytic intermediates, oxidoreductase
Biological source	Pseudomonas putida More
Total number of polymer chains	6
Total formula weight	150556.27
Authors	Knoot, C.J.,Purpero, V.M.,Lipscomb, J.D. (deposition date: 2014-09-23, release date: 2014-12-31, Last modification date: 2023-12-27)
Primary citation	Knoot, C.J.,Purpero, V.M.,Lipscomb, J.D. Crystal structures of alkylperoxo and anhydride intermediates in an intradiol ring-cleaving dioxygenase. Proc.Natl.Acad.Sci.USA, 112:388-393, 2015 Cited by PubMed: 25548185 DOI: 10.1073/pnas.1419118112 PDB entries with the same primary citation
Experimental method	X-RAY DIFFRACTION (1.78 Å)

Structure validation