RF5
Bonds
| First atom | Second atom | Bond order type | Distance (experimental model) | Distance (ideal model) | Properties |
| OP1 | P | doub | 1.48Å | 1.52Å | |
| OP2 | P | sing | 1.61Å | 1.51Å | |
| P | OP3 | sing | 1.61Å | 1.50Å | |
| P | O5 | sing | 1.61Å | 1.57Å | |
| O4 | C1 | sing | 1.44Å | 1.39Å | |
| C1 | O1 | sing | 1.43Å | 1.49Å | |
| C1 | C2 | sing | 1.54Å | 1.51Å | |
| C1 | H1 | sing | 1.09Å | 1.10Å | |
| O1 | HO1 | sing | 0.97Å | 0.95Å | |
| C3 | C2 | sing | 1.55Å | 1.50Å | |
| C2 | F2 | sing | 1.40Å | 1.36Å | |
| C2 | H2 | sing | 1.09Å | 1.10Å | |
| C4 | C3 | sing | 1.55Å | 1.51Å | |
| C3 | O3 | sing | 1.43Å | 1.41Å | |
| C3 | H3 | sing | 1.09Å | 1.10Å | |
| O3 | HO3 | sing | 0.97Å | 0.95Å | |
| C5 | C4 | sing | 1.53Å | 1.52Å | |
| C4 | O4 | sing | 1.44Å | 1.44Å | |
| C4 | H4 | sing | 1.09Å | 1.10Å | |
| O5 | C5 | sing | 1.43Å | 1.45Å | |
| C5 | H51 | sing | 1.09Å | 1.10Å | |
| C5 | H52 | sing | 1.09Å | 1.10Å | |
| OP2 | HOP2 | sing | 0.97Å | 0.95Å | |
| OP3 | HOP3 | sing | 0.97Å | 0.95Å |
Angles
| First atom | Second atom | Third atom | Angle (experimental model) | Angle (ideal model) |
| OP1 | P | OP2 | 114.9° | 109.4° |
| OP1 | P | OP3 | 109.9° | 109.5° |
| OP1 | P | O5 | 106.5° | 109.5° |
| OP2 | P | OP3 | 121.1° | 109.4° |
| OP2 | P | O5 | 100.8° | 109.5° |
| P | OP2 | HOP2 | 109.5° | 114.0° |
| OP3 | P | O5 | 101.0° | 109.5° |
| P | OP3 | HOP3 | 109.5° | 114.0° |
| P | O5 | C5 | 116.0° | 123.0° |
| O4 | C1 | O1 | 115.1° | 109.9° |
| O4 | C1 | C2 | 103.7° | 107.3° |
| O4 | C1 | H1 | 104.3° | 110.0° |
| C1 | O4 | C4 | 107.4° | 107.0° |
| O1 | C1 | C2 | 124.9° | 109.9° |
| O1 | C1 | H1 | 103.3° | 109.9° |
| C1 | O1 | HO1 | 109.5° | 114.0° |
| C2 | C1 | H1 | 103.1° | 109.8° |
| C1 | C2 | C3 | 105.3° | 104.2° |
| C1 | C2 | F2 | 104.5° | 110.5° |
| C1 | C2 | H2 | 109.8° | 110.5° |
| C3 | C2 | F2 | 114.7° | 110.5° |
| C3 | C2 | H2 | 109.9° | 110.6° |
| C2 | C3 | C4 | 97.4° | 102.1° |
| C2 | C3 | O3 | 105.4° | 110.9° |
| C2 | C3 | H3 | 113.4° | 110.9° |
| F2 | C2 | H2 | 112.1° | 110.5° |
| C4 | C3 | O3 | 110.9° | 110.9° |
| C4 | C3 | H3 | 113.2° | 110.9° |
| C3 | C4 | C5 | 115.1° | 110.6° |
| C3 | C4 | O4 | 99.4° | 103.5° |
| C3 | C4 | H4 | 109.5° | 110.6° |
| O3 | C3 | H3 | 115.0° | 110.8° |
| C3 | O3 | HO3 | 109.5° | 113.9° |
| C5 | C4 | O4 | 112.4° | 110.6° |
| C5 | C4 | H4 | 109.5° | 110.7° |
| C4 | C5 | O5 | 105.2° | 109.5° |
| C4 | C5 | H51 | 110.5° | 109.5° |
| C4 | C5 | H52 | 110.5° | 109.5° |
| O4 | C4 | H4 | 110.6° | 110.6° |
| O5 | C5 | H51 | 110.5° | 109.4° |
| O5 | C5 | H52 | 110.5° | 109.5° |
| H51 | C5 | H52 | 109.5° | 109.4° |
Dihedrals
| First atom | Second atom | Third atom | Fourth atom | Torsion (experimental model) | Torsion (ideal model) |
| OP1 | P | OP2 | OP3 | 135.9° | 119.9° |
| OP1 | P | OP2 | O5 | 114.1° | 120.0° |
| OP1 | P | OP3 | O5 | 112.2° | 120.0° |
| OP1 | P | O5 | C5 | 51.6° | 55.0° |
| OP1 | P | OP2 | HOP2 | 0.0° | 180.0° |
| OP1 | P | OP3 | HOP3 | 0.0° | 60.0° |
| OP2 | P | OP3 | O5 | 109.9° | 120.1° |
| OP2 | P | O5 | C5 | 68.6° | 64.9° |
| OP2 | P | OP3 | HOP3 | 137.8° | 60.0° |
| OP3 | P | O5 | C5 | 166.4° | 175.1° |
| OP3 | P | OP2 | HOP2 | 136.0° | 60.0° |
| P | O5 | C5 | C4 | 158.8° | 180.0° |
| P | O5 | C5 | H51 | 39.5° | 60.1° |
| P | O5 | C5 | H52 | 81.8° | 59.9° |
| O5 | P | OP2 | HOP2 | 114.0° | 60.0° |
| O5 | P | OP3 | HOP3 | 112.3° | 180.0° |
| O4 | C1 | O1 | C2 | 130.2° | 117.9° |
| O4 | C1 | O1 | H1 | 113.0° | 121.2° |
| O4 | C1 | C2 | H1 | 108.5° | 119.6° |
| O4 | C1 | O1 | HO1 | 180.0° | 62.2° |
| O4 | C1 | C2 | C3 | 8.2° | 2.1° |
| O4 | C1 | C2 | F2 | 129.5° | 116.6° |
| O4 | C1 | C2 | H2 | 110.1° | 120.8° |
| C1 | O4 | C4 | C3 | 47.9° | 40.1° |
| C1 | O4 | C4 | C5 | 170.2° | 158.6° |
| C1 | O4 | C4 | H4 | 67.1° | 78.4° |
| O1 | C1 | C2 | H1 | 116.9° | 121.0° |
| O1 | C1 | C2 | C3 | 142.9° | 117.4° |
| O1 | C1 | C2 | F2 | 95.9° | 123.9° |
| O1 | C1 | C2 | H2 | 24.5° | 1.4° |
| O1 | C1 | O4 | C4 | 115.1° | 92.9° |
| C2 | C1 | O1 | HO1 | 49.8° | 180.0° |
| C1 | C2 | C3 | F2 | 114.4° | 118.7° |
| C1 | C2 | C3 | H2 | 118.2° | 118.7° |
| C1 | C2 | F2 | H2 | 118.8° | 122.5° |
| C1 | C2 | C3 | C4 | 35.1° | 20.8° |
| C1 | C2 | C3 | O3 | 149.3° | 139.0° |
| C1 | C2 | C3 | H3 | 84.2° | 97.4° |
| C2 | C1 | O4 | C4 | 24.8° | 26.5° |
| H1 | C1 | O1 | HO1 | 67.0° | 59.0° |
| H1 | C1 | C2 | C3 | 100.3° | 121.6° |
| H1 | C1 | C2 | F2 | 21.0° | 2.9° |
| H1 | C1 | C2 | H2 | 141.4° | 119.6° |
| H1 | C1 | O4 | C4 | 132.4° | 146.0° |
| C3 | C2 | F2 | H2 | 126.3° | 122.7° |
| C2 | C3 | C4 | O3 | 109.7° | 118.2° |
| C2 | C3 | C4 | H3 | 119.4° | 118.2° |
| C2 | C3 | O3 | H3 | 125.6° | 123.6° |
| C2 | C3 | O3 | HO3 | 180.0° | 61.5° |
| C2 | C3 | C4 | C5 | 169.3° | 155.5° |
| C2 | C3 | C4 | O4 | 48.9° | 37.0° |
| C2 | C3 | C4 | H4 | 67.0° | 81.5° |
| F2 | C2 | C3 | C4 | 149.5° | 139.5° |
| F2 | C2 | C3 | O3 | 96.4° | 102.3° |
| F2 | C2 | C3 | H3 | 30.2° | 21.3° |
| H2 | C2 | C3 | C4 | 83.1° | 97.8° |
| H2 | C2 | C3 | O3 | 31.1° | 20.3° |
| H2 | C2 | C3 | H3 | 157.6° | 144.0° |
| C4 | C3 | O3 | H3 | 130.0° | 123.6° |
| C4 | C3 | O3 | HO3 | 75.6° | 174.2° |
| C3 | C4 | C5 | O4 | 112.9° | 114.1° |
| C3 | C4 | C5 | H4 | 123.8° | 122.9° |
| C3 | C4 | O4 | H4 | 115.1° | 118.5° |
| C3 | C4 | C5 | O5 | 59.1° | 175.0° |
| C3 | C4 | C5 | H51 | 178.4° | 55.0° |
| C3 | C4 | C5 | H52 | 60.2° | 65.0° |
| O3 | C3 | C4 | C5 | 81.1° | 86.3° |
| O3 | C3 | C4 | O4 | 158.6° | 155.2° |
| O3 | C3 | C4 | H4 | 42.7° | 36.7° |
| H3 | C3 | O3 | HO3 | 54.4° | 62.2° |
| H3 | C3 | C4 | C5 | 49.9° | 37.3° |
| H3 | C3 | C4 | O4 | 70.5° | 81.2° |
| H3 | C3 | C4 | H4 | 173.6° | 160.3° |
| C5 | C4 | O4 | H4 | 122.7° | 123.0° |
| C4 | C5 | O5 | H51 | 119.3° | 120.0° |
| C4 | C5 | O5 | H52 | 119.3° | 120.1° |
| C4 | C5 | H51 | H52 | 122.0° | 120.0° |
| O4 | C4 | C5 | O5 | 53.8° | 71.0° |
| O4 | C4 | C5 | H51 | 65.5° | 169.1° |
| O4 | C4 | C5 | H52 | 173.1° | 49.1° |
| H4 | C4 | C5 | O5 | 177.1° | 52.0° |
| H4 | C4 | C5 | H51 | 57.8° | 67.9° |
| H4 | C4 | C5 | H52 | 63.5° | 172.1° |
| O5 | C5 | H51 | H52 | 121.9° | 120.0° |
