NC1
Bonds
First atom | Second atom | Bond order type | Distance (experimental model) | Distance (ideal model) | Properties |
S1 | C2 | sing | 1.82Å | 1.83Å | |
S1 | C6 | sing | 1.82Å | 1.80Å | |
C2 | N3 | sing | 1.45Å | 1.46Å | |
C2 | C9 | sing | 1.52Å | 1.58Å | |
C2 | H9 | sing | 1.09Å | 1.11Å | |
N3 | C4 | sing | 1.38Å | 1.38Å | |
N3 | H8 | sing | 1.02Å | 1.02Å | |
C4 | C5 | doub | 1.35Å | 1.54Å | |
C4 | C19 | sing | 1.53Å | 1.54Å | |
C5 | C6 | sing | 1.52Å | 1.51Å | |
C5 | C22 | sing | 1.45Å | 1.47Å | |
C6 | H6 | sing | 1.10Å | 1.12Å | |
C6 | H7 | sing | 1.10Å | 1.12Å | |
C7 | O8 | doub | 1.23Å | 1.26Å | |
C7 | C9 | sing | 1.52Å | 1.55Å | |
C7 | OG | sing | 1.36Å | 1.37Å | |
C9 | N10 | sing | 1.44Å | 1.50Å | |
C9 | H10 | sing | 1.09Å | 1.12Å | |
N10 | C11 | sing | 1.39Å | 1.45Å | |
N10 | H11 | sing | 1.02Å | 1.02Å | |
C11 | O12 | doub | 1.23Å | 1.25Å | |
C11 | C13 | sing | 1.52Å | 1.52Å | |
C13 | C14 | sing | 1.51Å | 1.49Å | |
C13 | H12 | sing | 1.10Å | 1.12Å | |
C13 | H13 | sing | 1.10Å | 1.12Å | |
C14 | S15 | sing | 1.70Å | 1.66Å | Aromatic |
C14 | C18 | doub | 1.36Å | 1.48Å | Aromatic |
S15 | C16 | sing | 1.71Å | 1.71Å | Aromatic |
C16 | C17 | doub | 1.38Å | 1.36Å | Aromatic |
C16 | H14 | sing | 1.08Å | 1.10Å | |
C17 | C18 | sing | 1.42Å | 1.41Å | Aromatic |
C17 | H15 | sing | 1.08Å | 1.10Å | |
C18 | H16 | sing | 1.08Å | 1.10Å | |
C19 | O20 | doub | 1.26Å | 1.25Å | |
C19 | O21 | sing | 1.26Å | 1.22Å | |
C22 | C23 | doub | 1.33Å | 1.35Å | |
C22 | H5 | sing | 1.08Å | 1.10Å | |
C23 | C24 | sing | 1.47Å | 1.48Å | |
C23 | H4 | sing | 1.09Å | 1.10Å | |
C24 | C25 | doub | 1.39Å | 1.41Å | Aromatic |
C24 | C29 | sing | 1.39Å | 1.49Å | Aromatic |
C25 | C26 | sing | 1.39Å | 1.48Å | Aromatic |
C25 | N30 | sing | 1.42Å | 1.35Å | |
C26 | C27 | doub | 1.40Å | 1.36Å | Aromatic |
C26 | H1 | sing | 1.09Å | 1.10Å | |
C27 | C28 | sing | 1.40Å | 1.49Å | Aromatic |
C27 | N33 | sing | 1.42Å | 1.34Å | |
C28 | C29 | doub | 1.39Å | 1.36Å | Aromatic |
C28 | HC28 | sing | 1.09Å | 1.10Å | |
C29 | H3 | sing | 1.09Å | 1.10Å | |
N30 | O31 | sing | 1.25Å | 1.47Å | |
N30 | O32 | doub | 1.25Å | 1.36Å | |
N33 | O34 | sing | 1.26Å | 1.50Å | |
N33 | O35 | doub | 1.25Å | 1.37Å | |
N | CA | sing | 1.45Å | 1.46Å | |
N | H | sing | 1.00Å | 1.02Å | |
N | H2 | sing | 1.00Å | 1.02Å | |
CA | CB | sing | 1.53Å | 1.53Å | |
CA | C | sing | 1.54Å | 1.53Å | |
CA | H19 | sing | 1.10Å | 1.12Å | |
CB | OG | sing | 1.43Å | 1.43Å | |
CB | HB2 | sing | 1.10Å | 1.12Å | |
CB | HB3 | sing | 1.10Å | 1.11Å | |
C | O | doub | 1.26Å | 1.24Å | |
C | OXT | sing | 1.27Å | 90.83Å |
Angles
First atom | Second atom | Third atom | Angle (experimental model) | Angle (ideal model) |
C2 | S1 | C6 | 103.7° | 97.9° |
S1 | C2 | N3 | 115.0° | 110.8° |
S1 | C2 | C9 | 111.9° | 109.3° |
S1 | C2 | H9 | 103.7° | 108.5° |
S1 | C6 | C5 | 119.8° | 114.1° |
S1 | C6 | H6 | 108.5° | 106.0° |
S1 | C6 | H7 | 108.5° | 108.9° |
N3 | C2 | C9 | 109.6° | 109.8° |
N3 | C2 | H9 | 106.4° | 109.7° |
C2 | N3 | C4 | 129.4° | 125.7° |
C2 | N3 | H8 | 105.3° | 117.6° |
C9 | C2 | H9 | 109.9° | 108.8° |
C2 | C9 | C7 | 109.1° | 110.2° |
C2 | C9 | N10 | 112.2° | 109.9° |
C2 | C9 | H10 | 107.3° | 110.3° |
C4 | N3 | H8 | 105.3° | 115.8° |
N3 | C4 | C5 | 123.3° | 124.2° |
N3 | C4 | C19 | 113.7° | 114.8° |
C5 | C4 | C19 | 123.1° | 120.9° |
C4 | C5 | C6 | 118.3° | 122.4° |
C4 | C5 | C22 | 122.5° | 125.1° |
C4 | C19 | O20 | 123.2° | 114.3° |
C4 | C19 | O21 | 112.2° | 114.4° |
C6 | C5 | C22 | 119.2° | 112.5° |
C5 | C6 | H6 | 108.5° | 110.4° |
C5 | C6 | H7 | 108.5° | 109.9° |
C5 | C22 | C23 | 124.1° | 122.6° |
C5 | C22 | H5 | 122.6° | 114.6° |
H6 | C6 | H7 | 101.5° | 107.4° |
O8 | C7 | C9 | 122.2° | 122.7° |
O8 | C7 | OG | 127.7° | 125.1° |
C9 | C7 | OG | 110.1° | 112.2° |
C7 | C9 | N10 | 107.5° | 112.2° |
C7 | C9 | H10 | 112.0° | 107.5° |
C7 | OG | CB | 111.4° | 115.8° |
N10 | C9 | H10 | 108.8° | 106.6° |
C9 | N10 | C11 | 118.5° | 122.8° |
C9 | N10 | H11 | 122.4° | 118.6° |
C11 | N10 | H11 | 119.1° | 118.6° |
N10 | C11 | O12 | 123.6° | 124.8° |
N10 | C11 | C13 | 115.9° | 111.7° |
O12 | C11 | C13 | 120.5° | 123.5° |
C11 | C13 | C14 | 107.6° | 113.3° |
C11 | C13 | H12 | 112.9° | 108.8° |
C11 | C13 | H13 | 112.9° | 108.6° |
C14 | C13 | H12 | 112.9° | 109.6° |
C14 | C13 | H13 | 112.9° | 109.7° |
C13 | C14 | S15 | 119.0° | 118.7° |
C13 | C14 | C18 | 128.1° | 127.6° |
H12 | C13 | H13 | 97.6° | 106.6° |
S15 | C14 | C18 | 112.9° | 113.7° |
C14 | S15 | C16 | 93.9° | 91.0° |
C14 | C18 | C17 | 105.7° | 111.2° |
C14 | C18 | H16 | 128.9° | 124.4° |
S15 | C16 | C17 | 109.5° | 112.1° |
S15 | C16 | H14 | 134.5° | 120.4° |
C17 | C16 | H14 | 116.0° | 127.6° |
C16 | C17 | C18 | 118.1° | 112.0° |
C16 | C17 | H15 | 119.0° | 123.4° |
C18 | C17 | H15 | 122.9° | 124.5° |
C17 | C18 | H16 | 125.4° | 124.4° |
O20 | C19 | O21 | 124.6° | 131.3° |
C23 | C22 | H5 | 113.2° | 122.8° |
C22 | C23 | C24 | 121.3° | 124.6° |
C22 | C23 | H4 | 114.5° | 120.0° |
C24 | C23 | H4 | 124.2° | 115.5° |
C23 | C24 | C25 | 122.5° | 121.3° |
C23 | C24 | C29 | 118.7° | 117.7° |
C25 | C24 | C29 | 118.8° | 121.1° |
C24 | C25 | C26 | 118.9° | 119.4° |
C24 | C25 | N30 | 124.3° | 122.0° |
C24 | C29 | C28 | 120.9° | 119.5° |
C24 | C29 | H3 | 124.3° | 121.5° |
C26 | C25 | N30 | 116.8° | 118.6° |
C25 | C26 | C27 | 121.3° | 120.0° |
C25 | C26 | H1 | 123.8° | 120.1° |
C25 | N30 | O31 | 123.1° | 118.8° |
C25 | N30 | O32 | 119.4° | 118.8° |
C27 | C26 | H1 | 114.8° | 119.9° |
C26 | C27 | C28 | 119.7° | 120.0° |
C26 | C27 | N33 | 120.0° | 120.0° |
C28 | C27 | N33 | 120.3° | 120.0° |
C27 | C28 | C29 | 120.3° | 120.0° |
C27 | C28 | HC28 | 124.4° | 120.7° |
C27 | N33 | O34 | 120.3° | 119.0° |
C27 | N33 | O35 | 119.9° | 119.0° |
C29 | C28 | HC28 | 115.3° | 119.3° |
C28 | C29 | H3 | 114.8° | 119.0° |
O31 | N30 | O32 | 117.5° | 122.4° |
O34 | N33 | O35 | 119.8° | 122.0° |
CA | N | H | 112.0° | 118.8° |
CA | N | H2 | 110.1° | 118.8° |
N | CA | CB | 110.1° | 110.2° |
N | CA | C | 115.7° | 111.5° |
N | CA | H19 | 104.5° | 105.6° |
H | N | H2 | 112.0° | 121.1° |
CB | CA | C | 109.2° | 115.8° |
CB | CA | H19 | 111.7° | 107.5° |
CA | CB | OG | 111.3° | 111.3° |
CA | CB | HB2 | 111.5° | 111.5° |
CA | CB | HB3 | 111.5° | 110.4° |
C | CA | H19 | 105.6° | 105.6° |
CA | C | O | 120.1° | 116.4° |
CA | C | OXT | 117.8° | 114.7° |
OG | CB | HB2 | 111.5° | 108.4° |
OG | CB | HB3 | 111.5° | 107.4° |
HB2 | CB | HB3 | 98.9° | 107.7° |
O | C | OXT | 116.3° | 128.9° |
Dihedrals
First atom | Second atom | Third atom | Fourth atom | Torsion (experimental model) | Torsion (ideal model) |
S1 | C2 | N3 | C9 | 127.0° | 120.8° |
S1 | C2 | N3 | H9 | 114.2° | 119.7° |
S1 | C2 | C9 | H9 | 114.7° | 118.3° |
S1 | C2 | N3 | C4 | 16.1° | 37.3° |
S1 | C2 | N3 | H8 | 109.2° | 153.3° |
C2 | S1 | C6 | C5 | 35.8° | 46.6° |
C2 | S1 | C6 | H6 | 89.5° | 168.2° |
C2 | S1 | C6 | H7 | 161.0° | 76.5° |
S1 | C2 | C9 | C7 | 156.7° | 178.3° |
S1 | C2 | C9 | N10 | 37.7° | 57.5° |
S1 | C2 | C9 | H10 | 81.8° | 59.8° |
C6 | S1 | C2 | N3 | 30.7° | 51.1° |
C6 | S1 | C2 | C9 | 95.1° | 172.1° |
C6 | S1 | C2 | H9 | 146.5° | 69.4° |
S1 | C6 | C5 | C4 | 23.8° | 25.2° |
S1 | C6 | C5 | H6 | 125.3° | 119.2° |
S1 | C6 | C5 | H7 | 125.3° | 122.6° |
S1 | C6 | C5 | C22 | 155.2° | 155.4° |
S1 | C6 | H6 | H7 | 114.2° | 116.3° |
N3 | C2 | C9 | H9 | 116.5° | 120.0° |
C2 | N3 | C4 | H8 | 125.3° | 169.5° |
C2 | N3 | C4 | C5 | 1.5° | 6.5° |
C2 | N3 | C4 | C19 | 178.6° | 173.3° |
N3 | C2 | C9 | C7 | 27.9° | 60.0° |
N3 | C2 | C9 | N10 | 91.1° | 64.2° |
N3 | C2 | C9 | H10 | 149.4° | 178.5° |
C9 | C2 | N3 | C4 | 111.0° | 158.1° |
C9 | C2 | N3 | H8 | 123.8° | 32.6° |
C2 | C9 | C7 | O8 | 120.6° | 60.3° |
C2 | C9 | C7 | N10 | 121.9° | 122.9° |
C2 | C9 | C7 | H10 | 118.6° | 120.3° |
C2 | C9 | C7 | OG | 59.8° | 119.2° |
C2 | C9 | N10 | H10 | 118.5° | 119.6° |
C2 | C9 | N10 | C11 | 110.2° | 149.6° |
C2 | C9 | N10 | H11 | 69.8° | 30.4° |
H9 | C2 | N3 | C4 | 130.3° | 82.4° |
H9 | C2 | N3 | H8 | 5.0° | 86.9° |
H9 | C2 | C9 | C7 | 88.6° | 60.0° |
H9 | C2 | C9 | N10 | 152.4° | 175.8° |
H9 | C2 | C9 | H10 | 32.9° | 58.5° |
N3 | C4 | C5 | C19 | 179.9° | 179.8° |
N3 | C4 | C5 | C6 | 2.0° | 0.8° |
N3 | C4 | C5 | C22 | 177.0° | 178.5° |
N3 | C4 | C19 | O20 | 178.5° | 89.8° |
N3 | C4 | C19 | O21 | 0.9° | 90.3° |
H8 | N3 | C4 | C5 | 126.8° | 176.0° |
H8 | N3 | C4 | C19 | 53.3° | 3.7° |
C4 | C5 | C6 | C22 | 179.0° | 179.4° |
C4 | C5 | C6 | H6 | 101.5° | 144.4° |
C4 | C5 | C6 | H7 | 149.1° | 97.4° |
C5 | C4 | C19 | O20 | 1.4° | 90.0° |
C5 | C4 | C19 | O21 | 179.2° | 90.0° |
C4 | C5 | C22 | C23 | 178.1° | 180.0° |
C4 | C5 | C22 | H5 | 1.9° | 0.7° |
C19 | C4 | C5 | C6 | 177.9° | 179.5° |
C19 | C4 | C5 | C22 | 3.1° | 1.2° |
C4 | C19 | O20 | O21 | 179.4° | 180.0° |
C5 | C6 | H6 | H7 | 114.2° | 119.7° |
C6 | C5 | C22 | C23 | 2.9° | 0.6° |
C6 | C5 | C22 | H5 | 177.1° | 178.7° |
C22 | C5 | C6 | H6 | 79.5° | 36.2° |
C22 | C5 | C6 | H7 | 30.0° | 82.0° |
C5 | C22 | C23 | H5 | 180.0° | 179.2° |
C5 | C22 | C23 | C24 | 172.6° | 179.5° |
C5 | C22 | C23 | H4 | 7.4° | 0.7° |
O8 | C7 | C9 | OG | 179.7° | 179.5° |
O8 | C7 | C9 | N10 | 1.3° | 176.8° |
O8 | C7 | C9 | H10 | 120.8° | 59.9° |
O8 | C7 | OG | CB | 11.3° | 0.0° |
C7 | C9 | N10 | H10 | 121.5° | 117.4° |
C7 | C9 | N10 | C11 | 129.9° | 87.4° |
C7 | C9 | N10 | H11 | 50.1° | 92.6° |
C9 | C7 | OG | CB | 169.1° | 179.5° |
OG | C7 | C9 | N10 | 178.3° | 3.7° |
OG | C7 | C9 | H10 | 58.8° | 120.6° |
C7 | OG | CB | CA | 87.7° | 180.0° |
C7 | OG | CB | HB2 | 147.0° | 57.0° |
C7 | OG | CB | HB3 | 37.5° | 59.0° |
C9 | N10 | C11 | H11 | 180.0° | 179.9° |
C9 | N10 | C11 | O12 | 0.4° | 0.1° |
C9 | N10 | C11 | C13 | 178.3° | 179.8° |
H10 | C9 | N10 | C11 | 8.3° | 30.0° |
H10 | C9 | N10 | H11 | 171.7° | 150.0° |
N10 | C11 | O12 | C13 | 178.6° | 179.8° |
N10 | C11 | C13 | C14 | 80.9° | 177.9° |
N10 | C11 | C13 | H12 | 44.3° | 60.0° |
N10 | C11 | C13 | H13 | 153.8° | 55.6° |
H11 | N10 | C11 | O12 | 179.6° | 180.0° |
H11 | N10 | C11 | C13 | 1.8° | 0.2° |
O12 | C11 | C13 | C14 | 97.8° | 2.0° |
O12 | C11 | C13 | H12 | 136.9° | 120.2° |
O12 | C11 | C13 | H13 | 27.4° | 124.2° |
C11 | C13 | C14 | H12 | 125.2° | 121.7° |
C11 | C13 | C14 | H13 | 125.3° | 121.6° |
C11 | C13 | H12 | H13 | 118.9° | 116.9° |
C11 | C13 | C14 | S15 | 119.5° | 121.8° |
C11 | C13 | C14 | C18 | 60.2° | 58.2° |
C14 | C13 | H12 | H13 | 118.8° | 118.7° |
C13 | C14 | S15 | C18 | 179.7° | 180.0° |
C13 | C14 | S15 | C16 | 179.8° | 180.0° |
C13 | C14 | C18 | C17 | 179.7° | 180.0° |
C13 | C14 | C18 | H16 | 0.3° | 0.1° |
H12 | C13 | C14 | S15 | 5.8° | 0.0° |
H12 | C13 | C14 | C18 | 174.6° | 180.0° |
H13 | C13 | C14 | S15 | 115.3° | 116.7° |
H13 | C13 | C14 | C18 | 65.1° | 63.3° |
C14 | S15 | C16 | C17 | 0.1° | 0.0° |
C14 | S15 | C16 | H14 | 180.0° | 179.9° |
S15 | C14 | C18 | C17 | 0.0° | 0.0° |
S15 | C14 | C18 | H16 | 180.0° | 179.9° |
C18 | C14 | S15 | C16 | 0.0° | 0.0° |
C14 | C18 | C17 | C16 | 0.0° | 0.0° |
C14 | C18 | C17 | H16 | 180.0° | 179.9° |
C14 | C18 | C17 | H15 | 180.0° | 179.9° |
S15 | C16 | C17 | H14 | 180.0° | 179.9° |
S15 | C16 | C17 | C18 | 0.1° | 0.0° |
S15 | C16 | C17 | H15 | 179.9° | 179.9° |
C16 | C17 | C18 | H15 | 180.0° | 179.9° |
C16 | C17 | C18 | H16 | 180.0° | 179.9° |
H14 | C16 | C17 | C18 | 179.9° | 179.9° |
H14 | C16 | C17 | H15 | 0.1° | 0.0° |
H15 | C17 | C18 | H16 | 0.0° | 0.2° |
C22 | C23 | C24 | H4 | 180.0° | 178.9° |
C22 | C23 | C24 | C25 | 177.4° | 91.2° |
C22 | C23 | C24 | C29 | 3.1° | 88.9° |
H5 | C22 | C23 | C24 | 7.4° | 0.3° |
H5 | C22 | C23 | H4 | 172.6° | 178.6° |
C23 | C24 | C25 | C29 | 179.5° | 179.9° |
C23 | C24 | C25 | C26 | 179.1° | 180.0° |
C23 | C24 | C25 | N30 | 1.4° | 0.1° |
C23 | C24 | C29 | C28 | 179.3° | 180.0° |
C23 | C24 | C29 | H3 | 0.7° | 0.1° |
H4 | C23 | C24 | C25 | 2.6° | 89.9° |
H4 | C23 | C24 | C29 | 176.9° | 90.0° |
C24 | C25 | C26 | N30 | 179.6° | 180.0° |
C24 | C25 | C26 | C27 | 0.4° | 0.1° |
C24 | C25 | C26 | H1 | 179.6° | 180.0° |
C25 | C24 | C29 | C28 | 0.2° | 0.0° |
C25 | C24 | C29 | H3 | 179.8° | 180.0° |
C24 | C25 | N30 | O31 | 0.3° | 180.0° |
C24 | C25 | N30 | O32 | 179.5° | 0.1° |
C29 | C24 | C25 | C26 | 0.4° | 0.0° |
C29 | C24 | C25 | N30 | 179.1° | 180.0° |
C24 | C29 | C28 | C27 | 0.0° | 0.1° |
C24 | C29 | C28 | H3 | 180.0° | 180.0° |
C24 | C29 | C28 | HC28 | 180.0° | 179.9° |
C25 | C26 | C27 | H1 | 180.0° | 180.0° |
C25 | C26 | C27 | C28 | 0.1° | 0.1° |
C25 | C26 | C27 | N33 | 179.4° | 179.9° |
C26 | C25 | N30 | O31 | 179.3° | 0.0° |
C26 | C25 | N30 | O32 | 0.1° | 180.0° |
N30 | C25 | C26 | C27 | 179.2° | 180.0° |
N30 | C25 | C26 | H1 | 0.8° | 0.0° |
C25 | N30 | O31 | O32 | 179.2° | 179.9° |
C26 | C27 | C28 | N33 | 179.6° | 179.8° |
C26 | C27 | C28 | C29 | 0.1° | 0.1° |
C26 | C27 | C28 | HC28 | 180.0° | 179.9° |
C26 | C27 | N33 | O34 | 179.4° | 179.9° |
C26 | C27 | N33 | O35 | 0.2° | 0.1° |
H1 | C26 | C27 | C28 | 179.8° | 179.9° |
H1 | C26 | C27 | N33 | 0.6° | 0.1° |
C27 | C28 | C29 | HC28 | 180.0° | 180.0° |
C27 | C28 | C29 | H3 | 180.0° | 180.0° |
C28 | C27 | N33 | O34 | 0.1° | 0.1° |
C28 | C27 | N33 | O35 | 179.8° | 180.0° |
N33 | C27 | C28 | C29 | 179.6° | 179.9° |
N33 | C27 | C28 | HC28 | 0.4° | 0.1° |
C27 | N33 | O34 | O35 | 179.7° | 179.9° |
HC28 | C28 | C29 | H3 | 0.0° | 0.0° |
CA | N | H | H2 | 124.2° | 166.4° |
N | CA | CB | C | 128.0° | 127.6° |
N | CA | CB | H19 | 115.6° | 114.6° |
N | CA | C | H19 | 115.0° | 114.2° |
N | CA | CB | OG | 85.5° | 173.5° |
N | CA | CB | HB2 | 149.2° | 52.4° |
N | CA | CB | HB3 | 39.7° | 67.4° |
N | CA | C | O | 168.7° | 114.2° |
N | CA | C | OXT | 16.5° | 64.9° |
H | N | CA | CB | 54.7° | 117.3° |
H | N | CA | C | 179.0° | 112.7° |
H | N | CA | H19 | 65.3° | 1.5° |
H2 | N | CA | CB | 180.0° | 49.4° |
H2 | N | CA | C | 55.7° | 80.6° |
H2 | N | CA | H19 | 59.9° | 165.2° |
CB | CA | C | H19 | 120.2° | 118.8° |
CA | CB | OG | HB2 | 125.3° | 123.0° |
CA | CB | OG | HB3 | 125.2° | 121.0° |
CA | CB | HB2 | HB3 | 117.4° | 121.3° |
CB | CA | C | O | 66.5° | 118.8° |
CB | CA | C | OXT | 141.3° | 62.0° |
C | CA | CB | OG | 146.5° | 58.9° |
C | CA | CB | HB2 | 21.2° | 180.0° |
C | CA | CB | HB3 | 88.3° | 60.3° |
CA | C | O | OXT | 152.5° | 179.0° |
H19 | CA | CB | OG | 30.1° | 58.9° |
H19 | CA | CB | HB2 | 95.1° | 62.2° |
H19 | CA | CB | HB3 | 155.4° | 178.0° |
H19 | CA | C | O | 53.6° | 0.0° |
H19 | CA | C | OXT | 98.5° | 179.2° |
OG | CB | HB2 | HB3 | 117.4° | 115.8° |