N1R
Bonds
First atom | Second atom | Bond order type | Distance (experimental model) | Distance (ideal model) | Properties |
C01 | C02 | sing | 1.51Å | 1.52Å | |
N04 | C02 | sing | 1.35Å | 1.43Å | |
N04 | C05 | sing | 1.46Å | 1.45Å | |
C02 | O03 | doub | 1.21Å | 1.18Å | |
C06 | C05 | sing | 1.53Å | 1.53Å | |
C06 | C07 | sing | 1.53Å | 1.55Å | |
C10 | C09 | sing | 1.53Å | 1.52Å | |
C10 | N11 | sing | 1.47Å | 1.49Å | |
C26 | C25 | sing | 1.53Å | 1.53Å | |
C26 | C08 | sing | 1.53Å | 1.46Å | |
C25 | N11 | sing | 1.47Å | 1.49Å | |
C07 | C08 | sing | 1.53Å | 1.55Å | |
C09 | C08 | sing | 1.53Å | 1.50Å | |
N11 | C12 | sing | 1.35Å | 1.46Å | |
C15 | C14 | sing | 1.53Å | 1.52Å | |
C12 | O13 | doub | 1.21Å | 1.19Å | |
C12 | C14 | sing | 1.51Å | 1.54Å | |
C14 | O17 | sing | 1.43Å | 1.43Å | |
C14 | C16 | sing | 1.53Å | 1.53Å | |
O17 | C18 | sing | 1.36Å | 1.42Å | |
C18 | C24 | doub | 1.39Å | 1.39Å | Aromatic |
C18 | C19 | sing | 1.39Å | 1.39Å | Aromatic |
C24 | C23 | sing | 1.38Å | 1.38Å | Aromatic |
C19 | C20 | doub | 1.38Å | 1.38Å | Aromatic |
C23 | C21 | doub | 1.38Å | 1.39Å | Aromatic |
C20 | C21 | sing | 1.38Å | 1.37Å | Aromatic |
C21 | CL22 | sing | 1.74Å | 1.76Å | |
C10 | H101 | sing | 1.09Å | 1.10Å | |
C10 | H102 | sing | 1.09Å | 1.10Å | |
C15 | H153 | sing | 1.09Å | 1.10Å | |
C15 | H151 | sing | 1.09Å | 1.10Å | |
C15 | H152 | sing | 1.09Å | 1.10Å | |
C20 | H201 | sing | 1.08Å | 1.08Å | |
C24 | H241 | sing | 1.08Å | 1.08Å | |
C26 | H262 | sing | 1.09Å | 1.10Å | |
C26 | H261 | sing | 1.09Å | 1.10Å | |
C01 | H012 | sing | 1.09Å | 1.10Å | |
C01 | CL1 | sing | 1.80Å | 0.94Å | |
C01 | H011 | sing | 1.09Å | 1.10Å | |
C05 | H052 | sing | 1.09Å | 1.10Å | |
C05 | H051 | sing | 1.09Å | 1.10Å | |
C06 | H061 | sing | 1.09Å | 1.10Å | |
C06 | H062 | sing | 1.09Å | 1.10Å | |
C07 | H072 | sing | 1.09Å | 1.10Å | |
C07 | H071 | sing | 1.09Å | 1.10Å | |
C08 | H081 | sing | 1.09Å | 1.10Å | |
C09 | H091 | sing | 1.09Å | 1.10Å | |
C09 | H092 | sing | 1.09Å | 1.10Å | |
C16 | H163 | sing | 1.09Å | 1.10Å | |
C16 | H162 | sing | 1.09Å | 1.10Å | |
C16 | H161 | sing | 1.09Å | 1.10Å | |
C19 | H191 | sing | 1.08Å | 1.08Å | |
C23 | H231 | sing | 1.08Å | 1.08Å | |
C25 | H252 | sing | 1.09Å | 1.10Å | |
C25 | H251 | sing | 1.09Å | 1.10Å | |
N04 | H041 | sing | 0.97Å | 1.00Å |
Angles
First atom | Second atom | Third atom | Angle (experimental model) | Angle (ideal model) |
C01 | C02 | N04 | 117.3° | 120.0° |
C01 | C02 | O03 | 120.2° | 120.0° |
C02 | C01 | H012 | 109.5° | 109.4° |
C02 | C01 | CL1 | 109.5° | 109.5° |
C02 | C01 | H011 | 109.5° | 109.4° |
C02 | N04 | C05 | 120.3° | 120.1° |
N04 | C02 | O03 | 122.5° | 120.0° |
C02 | N04 | H041 | 119.8° | 120.0° |
N04 | C05 | C06 | 111.3° | 109.5° |
N04 | C05 | H052 | 109.0° | 109.4° |
N04 | C05 | H051 | 109.0° | 109.5° |
C05 | N04 | H041 | 119.9° | 120.0° |
C05 | C06 | C07 | 109.6° | 109.5° |
C06 | C05 | H052 | 109.0° | 109.5° |
C06 | C05 | H051 | 109.0° | 109.5° |
C05 | C06 | H061 | 109.4° | 109.5° |
C05 | C06 | H062 | 109.5° | 109.5° |
C06 | C07 | C08 | 122.7° | 109.5° |
C07 | C06 | H061 | 109.4° | 109.5° |
C07 | C06 | H062 | 109.4° | 109.4° |
C06 | C07 | H072 | 106.1° | 109.4° |
C06 | C07 | H071 | 106.1° | 109.4° |
C09 | C10 | N11 | 109.0° | 108.8° |
C10 | C09 | C08 | 115.5° | 109.3° |
C09 | C10 | H101 | 109.6° | 109.6° |
C09 | C10 | H102 | 109.6° | 109.6° |
C10 | C09 | H091 | 107.9° | 109.5° |
C10 | C09 | H092 | 107.9° | 109.5° |
C10 | N11 | C25 | 111.3° | 118.7° |
C10 | N11 | C12 | 124.9° | 120.6° |
N11 | C10 | H101 | 109.6° | 109.6° |
N11 | C10 | H102 | 109.6° | 109.6° |
C25 | C26 | C08 | 114.1° | 109.3° |
C26 | C25 | N11 | 115.5° | 108.8° |
C25 | C26 | H262 | 108.3° | 109.5° |
C25 | C26 | H261 | 108.3° | 109.5° |
C26 | C25 | H252 | 107.9° | 109.6° |
C26 | C25 | H251 | 107.9° | 109.6° |
C26 | C08 | C07 | 115.3° | 109.4° |
C26 | C08 | C09 | 117.8° | 109.5° |
C08 | C26 | H262 | 108.3° | 109.5° |
C08 | C26 | H261 | 108.3° | 109.5° |
C26 | C08 | H081 | 107.1° | 109.5° |
C25 | N11 | C12 | 123.8° | 120.6° |
N11 | C25 | H252 | 107.9° | 109.6° |
N11 | C25 | H251 | 107.9° | 109.6° |
C07 | C08 | C09 | 102.9° | 109.4° |
C08 | C07 | H072 | 106.0° | 109.5° |
C08 | C07 | H071 | 106.1° | 109.5° |
C07 | C08 | H081 | 106.2° | 109.5° |
C09 | C08 | H081 | 106.7° | 109.5° |
C08 | C09 | H091 | 107.9° | 109.5° |
C08 | C09 | H092 | 107.9° | 109.5° |
N11 | C12 | O13 | 117.6° | 120.0° |
N11 | C12 | C14 | 120.3° | 120.0° |
C15 | C14 | C12 | 108.3° | 109.5° |
C15 | C14 | O17 | 109.1° | 109.5° |
C15 | C14 | C16 | 109.7° | 109.5° |
C14 | C15 | H153 | 109.5° | 109.5° |
C14 | C15 | H151 | 109.5° | 109.5° |
C14 | C15 | H152 | 109.5° | 109.5° |
O13 | C12 | C14 | 122.1° | 120.0° |
C12 | C14 | O17 | 115.2° | 109.4° |
C12 | C14 | C16 | 107.7° | 109.5° |
O17 | C14 | C16 | 106.7° | 109.5° |
C14 | O17 | C18 | 122.6° | 117.0° |
C14 | C16 | H163 | 109.5° | 109.5° |
C14 | C16 | H162 | 109.5° | 109.5° |
C14 | C16 | H161 | 109.5° | 109.5° |
O17 | C18 | C24 | 117.6° | 120.1° |
O17 | C18 | C19 | 122.6° | 120.0° |
C24 | C18 | C19 | 119.8° | 119.9° |
C18 | C24 | C23 | 120.1° | 120.0° |
C18 | C24 | H241 | 120.0° | 120.0° |
C18 | C19 | C20 | 120.8° | 119.9° |
C18 | C19 | H191 | 119.6° | 120.0° |
C24 | C23 | C21 | 119.0° | 120.0° |
C23 | C24 | H241 | 119.9° | 120.0° |
C24 | C23 | H231 | 120.5° | 120.0° |
C19 | C20 | C21 | 118.3° | 120.1° |
C19 | C20 | H201 | 120.8° | 119.9° |
C20 | C19 | H191 | 119.6° | 120.0° |
C23 | C21 | C20 | 122.0° | 120.1° |
C23 | C21 | CL22 | 119.0° | 119.9° |
C21 | C23 | H231 | 120.5° | 120.0° |
C20 | C21 | CL22 | 119.0° | 119.9° |
C21 | C20 | H201 | 120.8° | 120.0° |
H101 | C10 | H102 | 109.5° | 109.7° |
H153 | C15 | H151 | 109.5° | 109.5° |
H153 | C15 | H152 | 109.5° | 109.5° |
H151 | C15 | H152 | 109.5° | 109.4° |
H262 | C26 | H261 | 109.5° | 109.5° |
H012 | C01 | CL1 | 109.5° | 109.5° |
H012 | C01 | H011 | 109.5° | 109.5° |
CL1 | C01 | H011 | 109.4° | 109.5° |
H052 | C05 | H051 | 109.5° | 109.4° |
H061 | C06 | H062 | 109.5° | 109.4° |
H072 | C07 | H071 | 109.5° | 109.5° |
H091 | C09 | H092 | 109.5° | 109.6° |
H163 | C16 | H162 | 109.4° | 109.5° |
H163 | C16 | H161 | 109.4° | 109.5° |
H162 | C16 | H161 | 109.5° | 109.5° |
H252 | C25 | H251 | 109.5° | 109.7° |
Dihedrals
First atom | Second atom | Third atom | Fourth atom | Torsion (experimental model) | Torsion (ideal model) |
C01 | C02 | N04 | O03 | 179.1° | 180.0° |
C01 | C02 | N04 | C05 | 177.9° | 180.0° |
C02 | C01 | H012 | CL1 | 120.0° | 120.0° |
C02 | C01 | H012 | H011 | 120.0° | 119.9° |
C02 | C01 | CL1 | H011 | 120.0° | 120.0° |
C01 | C02 | N04 | H041 | 2.1° | 0.1° |
C02 | N04 | C05 | H041 | 180.0° | 179.9° |
C02 | N04 | C05 | C06 | 176.0° | 180.0° |
N04 | C02 | C01 | H012 | 46.6° | 60.0° |
N04 | C02 | C01 | CL1 | 166.6° | 180.0° |
N04 | C02 | C01 | H011 | 73.4° | 60.0° |
C02 | N04 | C05 | H052 | 63.7° | 60.0° |
C02 | N04 | C05 | H051 | 55.7° | 59.9° |
C05 | N04 | C02 | O03 | 1.3° | 0.0° |
N04 | C05 | C06 | H052 | 120.3° | 120.0° |
N04 | C05 | C06 | H051 | 120.3° | 120.1° |
N04 | C05 | C06 | C07 | 67.6° | 180.0° |
N04 | C05 | H052 | H051 | 119.2° | 119.9° |
N04 | C05 | C06 | H061 | 52.4° | 60.0° |
N04 | C05 | C06 | H062 | 172.4° | 60.0° |
O03 | C02 | C01 | H012 | 132.6° | 120.0° |
O03 | C02 | C01 | CL1 | 12.6° | 0.0° |
O03 | C02 | C01 | H011 | 107.4° | 120.0° |
O03 | C02 | N04 | H041 | 178.7° | 180.0° |
C05 | C06 | C07 | H061 | 120.0° | 120.1° |
C05 | C06 | C07 | H062 | 120.0° | 120.0° |
C05 | C06 | C07 | C08 | 161.7° | 180.0° |
C06 | C05 | H052 | H051 | 119.1° | 120.0° |
C05 | C06 | H061 | H062 | 120.0° | 120.0° |
C05 | C06 | C07 | H072 | 39.9° | 60.0° |
C05 | C06 | C07 | H071 | 76.5° | 60.0° |
C06 | C05 | N04 | H041 | 4.0° | 0.1° |
C06 | C07 | C08 | C26 | 17.3° | 175.0° |
C06 | C07 | C08 | H072 | 121.8° | 120.0° |
C06 | C07 | C08 | H071 | 121.8° | 120.0° |
C06 | C07 | C08 | C09 | 146.9° | 65.0° |
C07 | C06 | C05 | H052 | 172.1° | 60.0° |
C07 | C06 | C05 | H051 | 52.7° | 59.9° |
C07 | C06 | H061 | H062 | 119.9° | 119.9° |
C06 | C07 | H072 | H071 | 114.1° | 119.9° |
C06 | C07 | C08 | H081 | 101.1° | 55.0° |
C09 | C10 | N11 | H101 | 119.9° | 119.8° |
C09 | C10 | N11 | H102 | 119.9° | 119.8° |
C10 | C09 | C08 | C26 | 16.9° | 61.4° |
C09 | C10 | N11 | C25 | 63.7° | 53.6° |
C10 | C09 | C08 | C07 | 144.9° | 178.6° |
C10 | C09 | C08 | H091 | 120.9° | 119.9° |
C10 | C09 | C08 | H092 | 120.9° | 119.9° |
C09 | C10 | N11 | C12 | 117.5° | 126.4° |
C09 | C10 | H101 | H102 | 120.2° | 120.4° |
C10 | C09 | C08 | H081 | 103.5° | 58.6° |
C10 | C09 | H091 | H092 | 117.3° | 120.1° |
C10 | N11 | C25 | C26 | 41.8° | 53.6° |
C10 | N11 | C25 | C12 | 178.8° | 180.0° |
N11 | C10 | C09 | C08 | 34.4° | 54.7° |
C10 | N11 | C12 | O13 | 1.7° | 5.5° |
C10 | N11 | C12 | C14 | 178.9° | 174.6° |
N11 | C10 | H101 | H102 | 120.2° | 120.4° |
N11 | C10 | C09 | H091 | 155.2° | 65.3° |
N11 | C10 | C09 | H092 | 86.5° | 174.6° |
C10 | N11 | C25 | H252 | 79.1° | 173.4° |
C10 | N11 | C25 | H251 | 162.7° | 66.1° |
C25 | C26 | C08 | H262 | 120.7° | 119.9° |
C25 | C26 | C08 | H261 | 120.7° | 119.9° |
C26 | C25 | N11 | H252 | 120.9° | 119.8° |
C26 | C25 | N11 | H251 | 120.9° | 119.7° |
C25 | C26 | C08 | C07 | 161.6° | 178.6° |
C25 | C26 | C08 | C09 | 39.7° | 61.4° |
C26 | C25 | N11 | C12 | 139.4° | 126.4° |
C25 | C26 | H262 | H261 | 117.9° | 120.0° |
C25 | C26 | C08 | H081 | 80.5° | 58.6° |
C26 | C25 | H252 | H251 | 117.2° | 120.3° |
C08 | C26 | C25 | N11 | 9.9° | 54.6° |
C26 | C08 | C07 | C09 | 129.6° | 120.0° |
C26 | C08 | C07 | H081 | 118.4° | 120.0° |
C26 | C08 | C09 | H081 | 120.4° | 120.1° |
C08 | C26 | H262 | H261 | 117.9° | 120.1° |
C26 | C08 | C07 | H072 | 139.2° | 65.0° |
C26 | C08 | C07 | H071 | 104.5° | 55.0° |
C26 | C08 | C09 | H091 | 104.0° | 58.5° |
C26 | C08 | C09 | H092 | 137.8° | 178.6° |
C08 | C26 | C25 | H252 | 130.7° | 174.5° |
C08 | C26 | C25 | H251 | 111.0° | 65.1° |
C25 | N11 | C12 | O13 | 179.6° | 174.6° |
C25 | N11 | C12 | C14 | 2.5° | 5.4° |
C25 | N11 | C10 | H101 | 176.4° | 66.1° |
C25 | N11 | C10 | H102 | 56.2° | 173.4° |
N11 | C25 | C26 | H262 | 130.5° | 65.3° |
N11 | C25 | C26 | H261 | 110.8° | 174.6° |
N11 | C25 | H252 | H251 | 117.3° | 120.4° |
C07 | C08 | C09 | H081 | 111.6° | 120.0° |
C07 | C08 | C26 | H262 | 77.7° | 61.4° |
C07 | C08 | C26 | H261 | 40.9° | 58.7° |
C08 | C07 | C06 | H061 | 78.3° | 59.9° |
C08 | C07 | C06 | H062 | 41.7° | 60.0° |
C08 | C07 | H072 | H071 | 114.0° | 120.1° |
C07 | C08 | C09 | H091 | 24.1° | 61.5° |
C07 | C08 | C09 | H092 | 94.2° | 58.7° |
C08 | C09 | C10 | H101 | 154.3° | 65.1° |
C08 | C09 | C10 | H102 | 85.5° | 174.5° |
C09 | C08 | C26 | H262 | 160.3° | 58.5° |
C09 | C08 | C26 | H261 | 81.0° | 178.7° |
C09 | C08 | C07 | H072 | 91.2° | 55.0° |
C09 | C08 | C07 | H071 | 25.1° | 175.1° |
C08 | C09 | H091 | H092 | 117.3° | 120.1° |
N11 | C12 | C14 | C15 | 73.5° | 78.7° |
N11 | C12 | O13 | C14 | 177.1° | 179.9° |
N11 | C12 | C14 | O17 | 49.0° | 41.3° |
N11 | C12 | C14 | C16 | 167.9° | 161.3° |
C12 | N11 | C10 | H101 | 2.4° | 113.8° |
C12 | N11 | C10 | H102 | 122.5° | 6.6° |
C12 | N11 | C25 | H252 | 99.7° | 6.6° |
C12 | N11 | C25 | H251 | 18.5° | 113.8° |
C15 | C14 | C12 | O13 | 109.5° | 101.3° |
C15 | C14 | C12 | O17 | 122.5° | 120.0° |
C15 | C14 | C12 | C16 | 118.6° | 120.1° |
C15 | C14 | O17 | C16 | 118.5° | 120.0° |
C15 | C14 | O17 | C18 | 161.8° | 175.1° |
C14 | C15 | H153 | H151 | 120.0° | 120.1° |
C14 | C15 | H153 | H152 | 120.0° | 120.0° |
C14 | C15 | H151 | H152 | 120.0° | 120.0° |
C15 | C14 | C16 | H163 | 180.0° | 64.2° |
C15 | C14 | C16 | H162 | 60.0° | 175.8° |
C15 | C14 | C16 | H161 | 60.0° | 55.8° |
O13 | C12 | C14 | O17 | 128.0° | 138.7° |
O13 | C12 | C14 | C16 | 9.1° | 18.8° |
C12 | C14 | O17 | C16 | 119.4° | 120.0° |
C12 | C14 | O17 | C18 | 39.7° | 55.1° |
C12 | C14 | C15 | H153 | 180.0° | 54.9° |
C12 | C14 | C15 | H151 | 60.0° | 174.9° |
C12 | C14 | C15 | H152 | 60.0° | 65.1° |
C12 | C14 | C16 | H163 | 62.3° | 175.8° |
C12 | C14 | C16 | H162 | 57.7° | 55.8° |
C12 | C14 | C16 | H161 | 177.7° | 64.2° |
C14 | O17 | C18 | C24 | 167.6° | 179.6° |
C14 | O17 | C18 | C19 | 11.5° | 0.4° |
O17 | C14 | C15 | H153 | 53.9° | 65.1° |
O17 | C14 | C15 | H151 | 174.0° | 55.0° |
O17 | C14 | C15 | H152 | 66.1° | 174.9° |
O17 | C14 | C16 | H163 | 61.9° | 55.8° |
O17 | C14 | C16 | H162 | 178.1° | 64.2° |
O17 | C14 | C16 | H161 | 58.1° | 175.8° |
C16 | C14 | O17 | C18 | 79.7° | 64.9° |
C16 | C14 | C15 | H153 | 62.7° | 174.9° |
C16 | C14 | C15 | H151 | 57.3° | 65.0° |
C16 | C14 | C15 | H152 | 177.3° | 54.9° |
C14 | C16 | H163 | H162 | 120.0° | 120.0° |
C14 | C16 | H163 | H161 | 120.0° | 120.0° |
C14 | C16 | H162 | H161 | 120.0° | 120.0° |
O17 | C18 | C24 | C19 | 179.2° | 179.2° |
O17 | C18 | C24 | C23 | 179.4° | 180.0° |
O17 | C18 | C19 | C20 | 179.5° | 179.7° |
O17 | C18 | C24 | H241 | 0.6° | 0.6° |
O17 | C18 | C19 | H191 | 0.5° | 0.3° |
C18 | C24 | C23 | H241 | 180.0° | 179.4° |
C24 | C18 | C19 | C20 | 0.4° | 0.5° |
C18 | C24 | C23 | C21 | 0.2° | 0.5° |
C24 | C18 | C19 | H191 | 179.6° | 179.6° |
C18 | C24 | C23 | H231 | 179.7° | 179.9° |
C19 | C18 | C24 | C23 | 0.2° | 0.8° |
C18 | C19 | C20 | H191 | 180.0° | 179.9° |
C18 | C19 | C20 | C21 | 0.6° | 0.0° |
C18 | C19 | C20 | H201 | 179.4° | 179.7° |
C19 | C18 | C24 | H241 | 179.8° | 179.8° |
C24 | C23 | C21 | H231 | 180.0° | 179.4° |
C24 | C23 | C21 | C20 | 0.5° | 0.0° |
C24 | C23 | C21 | CL22 | 179.8° | 180.0° |
C19 | C20 | C21 | C23 | 0.7° | 0.3° |
C19 | C20 | C21 | H201 | 180.0° | 179.7° |
C19 | C20 | C21 | CL22 | 179.9° | 179.7° |
C23 | C21 | C20 | CL22 | 179.3° | 180.0° |
C23 | C21 | C20 | H201 | 179.4° | 180.0° |
C21 | C23 | C24 | H241 | 179.7° | 180.0° |
C21 | C20 | C19 | H191 | 179.4° | 179.9° |
C20 | C21 | C23 | H231 | 179.5° | 179.4° |
CL22 | C21 | C20 | H201 | 0.1° | 0.1° |
CL22 | C21 | C23 | H231 | 0.2° | 0.6° |
H101 | C10 | C09 | H091 | 84.9° | 174.9° |
H101 | C10 | C09 | H092 | 33.4° | 54.8° |
H102 | C10 | C09 | H091 | 35.3° | 54.5° |
H102 | C10 | C09 | H092 | 153.6° | 65.6° |
H153 | C15 | H151 | H152 | 120.0° | 120.0° |
H201 | C20 | C19 | H191 | 0.6° | 0.2° |
H241 | C24 | C23 | H231 | 0.3° | 0.6° |
H262 | C26 | C08 | H081 | 40.2° | 178.6° |
H262 | C26 | C25 | H252 | 108.6° | 54.5° |
H262 | C26 | C25 | H251 | 9.6° | 174.9° |
H261 | C26 | C08 | H081 | 158.8° | 61.3° |
H261 | C26 | C25 | H252 | 10.1° | 65.6° |
H261 | C26 | C25 | H251 | 128.3° | 54.9° |
H012 | C01 | CL1 | H011 | 120.0° | 120.0° |
H052 | C05 | C06 | H061 | 67.9° | 60.0° |
H052 | C05 | C06 | H062 | 52.1° | 180.0° |
H052 | C05 | N04 | H041 | 116.3° | 120.1° |
H051 | C05 | C06 | H061 | 172.7° | 180.0° |
H051 | C05 | C06 | H062 | 67.3° | 60.0° |
H051 | C05 | N04 | H041 | 124.2° | 120.0° |
H061 | C06 | C07 | H072 | 159.9° | 180.0° |
H061 | C06 | C07 | H071 | 43.5° | 60.1° |
H062 | C06 | C07 | H072 | 80.1° | 60.0° |
H062 | C06 | C07 | H071 | 163.5° | 180.0° |
H072 | C07 | C08 | H081 | 20.7° | 175.0° |
H071 | C07 | C08 | H081 | 137.1° | 65.0° |
H081 | C08 | C09 | H091 | 135.6° | 178.6° |
H081 | C08 | C09 | H092 | 17.4° | 61.3° |
H163 | C16 | H162 | H161 | 119.9° | 120.0° |