FPO
Bonds
| First atom | Second atom | Bond order type | Distance (experimental model) | Distance (ideal model) | Properties |
| P | O1 | doub | 1.57Å | 1.53Å | |
| P | O2 | sing | 1.57Å | 1.51Å | |
| P | O3 | sing | 1.57Å | 1.49Å | |
| P | F | sing | 1.67Å | 1.58Å |
Angles
| First atom | Second atom | Third atom | Angle (experimental model) | Angle (ideal model) |
| O1 | P | O2 | 117.6° | 109.5° |
| O1 | P | O3 | 113.4° | 109.5° |
| O1 | P | F | 104.0° | 109.5° |
| O2 | P | O3 | 113.2° | 109.5° |
| O2 | P | F | 101.8° | 109.5° |
| O3 | P | F | 104.7° | 109.5° |
Dihedrals
| First atom | Second atom | Third atom | Fourth atom | Torsion (experimental model) | Torsion (ideal model) |
| O1 | P | O2 | O3 | 135.4° | 120.0° |
| O1 | P | O2 | F | 112.8° | 120.0° |
| O1 | P | O3 | F | 112.8° | 120.0° |
| O2 | P | O3 | F | 110.0° | 120.0° |






