9XW
Bonds
First atom | Second atom | Bond order type | Distance (experimental model) | Distance (ideal model) | Properties |
C23 | C22 | sing | 1.53Å | 1.52Å | |
C11 | C12 | sing | 1.53Å | 1.51Å | |
C11 | O10 | sing | 1.43Å | 1.44Å | |
C12 | N07 | sing | 1.47Å | 1.41Å | |
O10 | C09 | sing | 1.43Å | 1.43Å | |
C21 | C22 | sing | 1.53Å | 1.51Å | |
C21 | C20 | sing | 1.53Å | 1.52Å | |
C22 | C25 | sing | 1.53Å | 1.50Å | |
C22 | O24 | sing | 1.43Å | 1.42Å | |
C25 | C26 | sing | 1.53Å | 1.51Å | |
N07 | C06 | sing | 1.40Å | 1.45Å | |
N07 | C08 | sing | 1.47Å | 1.43Å | |
C09 | C08 | sing | 1.53Å | 1.50Å | |
O18 | C17 | doub | 1.22Å | 1.22Å | |
C20 | N19 | sing | 1.47Å | 1.44Å | |
S14 | C13 | sing | 1.76Å | 1.73Å | Aromatic |
S14 | C15 | sing | 1.76Å | 1.75Å | Aromatic |
C17 | N19 | sing | 1.35Å | 1.48Å | |
C17 | N16 | sing | 1.35Å | 1.45Å | |
C06 | C13 | doub | 1.40Å | 1.41Å | Aromatic |
C06 | C05 | sing | 1.38Å | 1.40Å | Aromatic |
N19 | C26 | sing | 1.47Å | 1.46Å | |
C13 | C28 | sing | 1.40Å | 1.40Å | Aromatic |
C15 | N16 | sing | 1.39Å | 1.44Å | |
C15 | N27 | doub | 1.29Å | 1.33Å | Aromatic |
C05 | C04 | doub | 1.39Å | 1.43Å | Aromatic |
C28 | N27 | sing | 1.35Å | 1.36Å | Aromatic |
C28 | C03 | doub | 1.42Å | 1.43Å | Aromatic |
C04 | C03 | sing | 1.38Å | 1.36Å | Aromatic |
C03 | O02 | sing | 1.36Å | 1.44Å | |
C01 | O02 | sing | 1.43Å | 1.46Å | |
C20 | H1 | sing | 1.09Å | 1.10Å | |
C20 | H2 | sing | 1.09Å | 1.10Å | |
C21 | H3 | sing | 1.09Å | 1.10Å | |
C21 | H4 | sing | 1.09Å | 1.10Å | |
C26 | H5 | sing | 1.09Å | 1.10Å | |
C26 | H6 | sing | 1.09Å | 1.10Å | |
C01 | H7 | sing | 1.09Å | 1.10Å | |
C01 | H8 | sing | 1.09Å | 1.10Å | |
C01 | H9 | sing | 1.09Å | 1.10Å | |
C04 | H10 | sing | 1.08Å | 1.08Å | |
C05 | H11 | sing | 1.08Å | 1.08Å | |
C08 | H12 | sing | 1.09Å | 1.10Å | |
C08 | H13 | sing | 1.09Å | 1.10Å | |
C09 | H14 | sing | 1.09Å | 1.10Å | |
C09 | H15 | sing | 1.09Å | 1.10Å | |
C11 | H16 | sing | 1.09Å | 1.10Å | |
C11 | H17 | sing | 1.09Å | 1.10Å | |
C12 | H18 | sing | 1.09Å | 1.10Å | |
C12 | H19 | sing | 1.09Å | 1.10Å | |
C23 | H20 | sing | 1.09Å | 1.10Å | |
C23 | H21 | sing | 1.09Å | 1.10Å | |
C23 | H22 | sing | 1.09Å | 1.10Å | |
C25 | H23 | sing | 1.09Å | 1.10Å | |
C25 | H24 | sing | 1.09Å | 1.10Å | |
N16 | H25 | sing | 0.97Å | 1.00Å | |
O24 | H26 | sing | 0.97Å | 0.95Å |
Angles
First atom | Second atom | Third atom | Angle (experimental model) | Angle (ideal model) |
C23 | C22 | C21 | 109.1° | 109.5° |
C23 | C22 | C25 | 107.6° | 109.4° |
C23 | C22 | O24 | 109.0° | 109.5° |
C22 | C23 | H20 | 109.5° | 109.4° |
C22 | C23 | H21 | 109.4° | 109.5° |
C22 | C23 | H22 | 109.5° | 109.5° |
C12 | C11 | O10 | 111.6° | 109.3° |
C11 | C12 | N07 | 112.9° | 109.2° |
C12 | C11 | H16 | 108.9° | 109.5° |
C12 | C11 | H17 | 108.9° | 109.5° |
C11 | C12 | H18 | 108.6° | 109.5° |
C11 | C12 | H19 | 108.6° | 109.6° |
C11 | O10 | C09 | 111.6° | 113.7° |
O10 | C11 | H16 | 109.0° | 109.6° |
O10 | C11 | H17 | 108.9° | 109.4° |
C12 | N07 | C06 | 120.6° | 111.0° |
C12 | N07 | C08 | 114.2° | 110.8° |
N07 | C12 | H18 | 108.6° | 109.5° |
N07 | C12 | H19 | 108.6° | 109.5° |
O10 | C09 | C08 | 111.4° | 109.3° |
O10 | C09 | H14 | 109.0° | 109.5° |
O10 | C09 | H15 | 109.0° | 109.6° |
C22 | C21 | C20 | 112.5° | 109.3° |
C21 | C22 | C25 | 113.5° | 109.5° |
C21 | C22 | O24 | 108.7° | 109.5° |
C22 | C21 | H3 | 108.7° | 109.5° |
C22 | C21 | H4 | 108.7° | 109.5° |
C21 | C20 | N19 | 107.7° | 108.8° |
C21 | C20 | H1 | 109.9° | 109.6° |
C21 | C20 | H2 | 109.9° | 109.7° |
C20 | C21 | H3 | 108.7° | 109.5° |
C20 | C21 | H4 | 108.7° | 109.5° |
C25 | C22 | O24 | 108.8° | 109.5° |
C22 | C25 | C26 | 112.1° | 109.3° |
C22 | C25 | H23 | 108.8° | 109.5° |
C22 | C25 | H24 | 108.8° | 109.5° |
C22 | O24 | H26 | 109.5° | 114.0° |
C25 | C26 | N19 | 109.1° | 108.8° |
C25 | C26 | H5 | 109.6° | 109.6° |
C25 | C26 | H6 | 109.6° | 109.6° |
C26 | C25 | H23 | 108.8° | 109.5° |
C26 | C25 | H24 | 108.8° | 109.5° |
C06 | N07 | C08 | 119.5° | 111.0° |
N07 | C06 | C13 | 121.2° | 119.9° |
N07 | C06 | C05 | 119.5° | 119.9° |
N07 | C08 | C09 | 113.1° | 109.3° |
N07 | C08 | H12 | 108.6° | 109.4° |
N07 | C08 | H13 | 108.5° | 109.5° |
C09 | C08 | H12 | 108.5° | 109.5° |
C09 | C08 | H13 | 108.6° | 109.5° |
C08 | C09 | H14 | 109.0° | 109.5° |
C08 | C09 | H15 | 109.0° | 109.5° |
O18 | C17 | N19 | 119.9° | 120.0° |
O18 | C17 | N16 | 122.5° | 120.0° |
C20 | N19 | C17 | 123.7° | 120.6° |
C20 | N19 | C26 | 114.0° | 118.7° |
N19 | C20 | H1 | 109.9° | 109.6° |
N19 | C20 | H2 | 109.9° | 109.6° |
C13 | S14 | C15 | 95.4° | 90.4° |
S14 | C13 | C06 | 135.7° | 131.2° |
S14 | C13 | C28 | 104.6° | 108.4° |
S14 | C15 | N16 | 127.4° | 124.8° |
S14 | C15 | N27 | 107.4° | 110.4° |
N19 | C17 | N16 | 117.6° | 120.0° |
C17 | N19 | C26 | 122.3° | 120.7° |
C17 | N16 | C15 | 123.2° | 120.0° |
C17 | N16 | H25 | 118.4° | 120.0° |
C13 | C06 | C05 | 119.3° | 120.2° |
C06 | C13 | C28 | 119.7° | 120.4° |
C06 | C05 | C04 | 120.6° | 119.9° |
C06 | C05 | H11 | 119.7° | 120.1° |
N19 | C26 | H5 | 109.5° | 109.5° |
N19 | C26 | H6 | 109.6° | 109.7° |
C13 | C28 | N27 | 117.3° | 112.9° |
C13 | C28 | C03 | 120.6° | 118.4° |
N16 | C15 | N27 | 125.2° | 124.8° |
C15 | N16 | H25 | 118.4° | 120.0° |
C15 | N27 | C28 | 115.3° | 117.9° |
C05 | C04 | C03 | 119.8° | 120.6° |
C05 | C04 | H10 | 120.1° | 119.7° |
C04 | C05 | H11 | 119.7° | 120.0° |
N27 | C28 | C03 | 122.1° | 128.7° |
C28 | C03 | C04 | 120.0° | 120.5° |
C28 | C03 | O02 | 119.7° | 119.7° |
C04 | C03 | O02 | 120.3° | 119.8° |
C03 | C04 | H10 | 120.1° | 119.7° |
C03 | O02 | C01 | 113.4° | 117.0° |
O02 | C01 | H7 | 109.5° | 109.4° |
O02 | C01 | H8 | 109.5° | 109.4° |
O02 | C01 | H9 | 109.5° | 109.5° |
H1 | C20 | H2 | 109.5° | 109.6° |
H3 | C21 | H4 | 109.5° | 109.5° |
H5 | C26 | H6 | 109.5° | 109.6° |
H7 | C01 | H8 | 109.5° | 109.5° |
H7 | C01 | H9 | 109.4° | 109.5° |
H8 | C01 | H9 | 109.5° | 109.5° |
H12 | C08 | H13 | 109.5° | 109.6° |
H14 | C09 | H15 | 109.5° | 109.5° |
H16 | C11 | H17 | 109.5° | 109.5° |
H18 | C12 | H19 | 109.5° | 109.6° |
H20 | C23 | H21 | 109.5° | 109.5° |
H20 | C23 | H22 | 109.4° | 109.4° |
H21 | C23 | H22 | 109.5° | 109.5° |
H23 | C25 | H24 | 109.5° | 109.5° |
Dihedrals
First atom | Second atom | Third atom | Fourth atom | Torsion (experimental model) | Torsion (ideal model) |
C23 | C22 | C21 | C25 | 120.0° | 120.0° |
C23 | C22 | C21 | O24 | 118.7° | 120.0° |
C23 | C22 | C21 | C20 | 167.9° | 178.6° |
C23 | C22 | C25 | O24 | 118.0° | 120.0° |
C23 | C22 | C25 | C26 | 167.6° | 178.6° |
C23 | C22 | C21 | H3 | 71.7° | 61.4° |
C23 | C22 | C21 | H4 | 47.4° | 58.7° |
C22 | C23 | H20 | H21 | 120.0° | 120.0° |
C22 | C23 | H20 | H22 | 120.0° | 120.0° |
C22 | C23 | H21 | H22 | 120.0° | 120.0° |
C23 | C22 | C25 | H23 | 47.2° | 61.4° |
C23 | C22 | C25 | H24 | 72.0° | 58.7° |
C23 | C22 | O24 | H26 | 180.0° | 60.0° |
C12 | C11 | O10 | H16 | 120.3° | 119.9° |
C12 | C11 | O10 | H17 | 120.3° | 119.9° |
C11 | C12 | N07 | H18 | 120.5° | 119.9° |
C11 | C12 | N07 | H19 | 120.5° | 119.9° |
C12 | C11 | O10 | C09 | 55.1° | 58.7° |
C11 | C12 | N07 | C06 | 158.7° | 177.6° |
C11 | C12 | N07 | C08 | 48.3° | 58.6° |
C12 | C11 | H16 | H17 | 119.0° | 120.1° |
C11 | C12 | H18 | H19 | 118.5° | 120.2° |
O10 | C11 | C12 | N07 | 51.5° | 56.8° |
C11 | O10 | C09 | C08 | 55.0° | 58.7° |
C11 | O10 | C09 | H14 | 175.4° | 61.3° |
C11 | O10 | C09 | H15 | 65.2° | 178.6° |
O10 | C11 | H16 | H17 | 119.0° | 120.1° |
O10 | C11 | C12 | H18 | 172.0° | 176.7° |
O10 | C11 | C12 | H19 | 69.0° | 63.1° |
C12 | N07 | C06 | C08 | 151.7° | 123.7° |
C12 | N07 | C08 | C09 | 48.4° | 58.6° |
C12 | N07 | C06 | C13 | 50.7° | 120.0° |
C12 | N07 | C06 | C05 | 129.3° | 60.2° |
C12 | N07 | C08 | H12 | 169.0° | 61.3° |
C12 | N07 | C08 | H13 | 72.1° | 178.6° |
N07 | C12 | C11 | H16 | 171.8° | 176.8° |
N07 | C12 | C11 | H17 | 68.9° | 63.1° |
N07 | C12 | H18 | H19 | 118.4° | 120.1° |
O10 | C09 | C08 | N07 | 51.3° | 56.8° |
O10 | C09 | C08 | H14 | 120.3° | 120.0° |
O10 | C09 | C08 | H15 | 120.3° | 120.0° |
O10 | C09 | C08 | H12 | 171.9° | 63.0° |
O10 | C09 | C08 | H13 | 69.2° | 176.8° |
O10 | C09 | H14 | H15 | 119.1° | 120.1° |
C09 | O10 | C11 | H16 | 175.4° | 178.6° |
C09 | O10 | C11 | H17 | 65.2° | 61.3° |
C22 | C21 | C20 | H3 | 120.4° | 120.0° |
C22 | C21 | C20 | H4 | 120.5° | 119.9° |
C21 | C22 | C25 | O24 | 121.2° | 120.0° |
C21 | C22 | C25 | C26 | 46.7° | 61.4° |
C22 | C21 | C20 | N19 | 53.7° | 54.7° |
C22 | C21 | C20 | H1 | 66.1° | 65.2° |
C22 | C21 | C20 | H2 | 173.4° | 174.5° |
C22 | C21 | H3 | H4 | 118.6° | 120.1° |
C21 | C22 | C23 | H20 | 180.0° | 60.0° |
C21 | C22 | C23 | H21 | 60.0° | 180.0° |
C21 | C22 | C23 | H22 | 60.0° | 59.9° |
C21 | C22 | C25 | H23 | 73.7° | 58.6° |
C21 | C22 | C25 | H24 | 167.1° | 178.7° |
C21 | C22 | O24 | H26 | 61.2° | 180.0° |
C20 | C21 | C22 | C25 | 47.9° | 61.4° |
C20 | C21 | C22 | O24 | 73.4° | 58.6° |
C21 | C20 | N19 | H1 | 119.7° | 119.8° |
C21 | C20 | N19 | H2 | 119.7° | 119.9° |
C21 | C20 | N19 | C17 | 115.6° | 126.4° |
C21 | C20 | N19 | C26 | 62.6° | 53.6° |
C21 | C20 | H1 | H2 | 120.8° | 120.4° |
C20 | C21 | H3 | H4 | 118.6° | 120.1° |
C22 | C25 | C26 | H23 | 120.4° | 119.9° |
C22 | C25 | C26 | H24 | 120.4° | 119.9° |
C22 | C25 | C26 | N19 | 51.7° | 54.7° |
C25 | C22 | C21 | H3 | 168.3° | 58.6° |
C25 | C22 | C21 | H4 | 72.6° | 178.7° |
C22 | C25 | C26 | H5 | 171.6° | 174.4° |
C22 | C25 | C26 | H6 | 68.3° | 65.3° |
C25 | C22 | C23 | H20 | 56.4° | 180.0° |
C25 | C22 | C23 | H21 | 63.6° | 60.0° |
C25 | C22 | C23 | H22 | 176.4° | 60.1° |
C22 | C25 | H23 | H24 | 118.8° | 120.1° |
C25 | C22 | O24 | H26 | 62.9° | 60.0° |
O24 | C22 | C25 | C26 | 74.5° | 58.6° |
O24 | C22 | C21 | H3 | 47.1° | 178.6° |
O24 | C22 | C21 | H4 | 166.2° | 61.3° |
O24 | C22 | C23 | H20 | 61.4° | 60.0° |
O24 | C22 | C23 | H21 | 178.6° | 60.0° |
O24 | C22 | C23 | H22 | 58.6° | 179.9° |
O24 | C22 | C25 | H23 | 165.1° | 178.6° |
O24 | C22 | C25 | H24 | 45.9° | 61.3° |
C25 | C26 | N19 | C20 | 62.4° | 53.6° |
C25 | C26 | N19 | C17 | 115.8° | 126.4° |
C25 | C26 | N19 | H5 | 119.9° | 119.8° |
C25 | C26 | N19 | H6 | 120.0° | 119.9° |
C25 | C26 | H5 | H6 | 120.2° | 120.4° |
C26 | C25 | H23 | H24 | 118.8° | 120.1° |
C06 | N07 | C08 | C09 | 158.2° | 177.6° |
N07 | C06 | C13 | S14 | 0.1° | 0.3° |
N07 | C06 | C13 | C05 | 180.0° | 179.8° |
N07 | C06 | C13 | C28 | 180.0° | 179.9° |
N07 | C06 | C05 | C04 | 180.0° | 180.0° |
N07 | C06 | C05 | H11 | 0.1° | 0.1° |
C06 | N07 | C08 | H12 | 37.7° | 62.5° |
C06 | N07 | C08 | H13 | 81.2° | 57.6° |
C06 | N07 | C12 | H18 | 38.2° | 57.7° |
C06 | N07 | C12 | H19 | 80.8° | 62.5° |
N07 | C08 | C09 | H12 | 120.6° | 119.9° |
N07 | C08 | C09 | H13 | 120.5° | 120.0° |
C08 | N07 | C06 | C13 | 101.0° | 116.3° |
C08 | N07 | C06 | C05 | 79.0° | 63.5° |
N07 | C08 | H12 | H13 | 118.3° | 120.1° |
N07 | C08 | C09 | H14 | 171.6° | 63.1° |
N07 | C08 | C09 | H15 | 69.0° | 176.8° |
C08 | N07 | C12 | H18 | 168.8° | 178.5° |
C08 | N07 | C12 | H19 | 72.2° | 61.4° |
C09 | C08 | H12 | H13 | 118.3° | 120.1° |
C08 | C09 | H14 | H15 | 119.1° | 120.0° |
O18 | C17 | N19 | C20 | 1.3° | 5.0° |
O18 | C17 | N19 | N16 | 180.0° | 180.0° |
O18 | C17 | N19 | C26 | 179.3° | 175.0° |
O18 | C17 | N16 | C15 | 0.5° | 5.1° |
O18 | C17 | N16 | H25 | 179.4° | 174.9° |
C20 | N19 | C17 | C26 | 178.0° | 180.0° |
C20 | N19 | C17 | N16 | 178.8° | 175.0° |
N19 | C20 | H1 | H2 | 120.8° | 120.3° |
N19 | C20 | C21 | H3 | 174.1° | 65.3° |
N19 | C20 | C21 | H4 | 66.8° | 174.6° |
C20 | N19 | C26 | H5 | 177.6° | 173.4° |
C20 | N19 | C26 | H6 | 57.5° | 66.3° |
S14 | C13 | C06 | C28 | 179.9° | 179.8° |
S14 | C13 | C06 | C05 | 179.9° | 179.9° |
C13 | S14 | C15 | N16 | 180.0° | 179.9° |
C13 | S14 | C15 | N27 | 0.3° | 0.2° |
S14 | C13 | C28 | N27 | 0.1° | 0.2° |
S14 | C13 | C28 | C03 | 179.9° | 179.8° |
S14 | C15 | N16 | C17 | 6.4° | 179.8° |
C15 | S14 | C13 | C06 | 179.9° | 180.0° |
C15 | S14 | C13 | C28 | 0.2° | 0.2° |
S14 | C15 | N16 | N27 | 179.6° | 179.8° |
S14 | C15 | N27 | C28 | 0.3° | 0.2° |
S14 | C15 | N16 | H25 | 173.6° | 0.2° |
N19 | C17 | N16 | C15 | 179.4° | 174.9° |
C17 | N19 | C20 | H1 | 124.7° | 113.8° |
C17 | N19 | C20 | H2 | 4.1° | 6.5° |
C17 | N19 | C26 | H5 | 4.1° | 6.6° |
C17 | N19 | C26 | H6 | 124.2° | 113.7° |
N19 | C17 | N16 | H25 | 0.6° | 5.1° |
N16 | C17 | N19 | C26 | 0.7° | 5.0° |
C17 | N16 | C15 | H25 | 180.0° | 180.0° |
C17 | N16 | C15 | N27 | 174.0° | 0.0° |
C13 | C06 | C05 | C04 | 0.0° | 0.1° |
C06 | C13 | C28 | N27 | 180.0° | 180.0° |
C06 | C13 | C28 | C03 | 0.1° | 0.0° |
C13 | C06 | C05 | H11 | 179.9° | 179.9° |
C05 | C06 | C13 | C28 | 0.0° | 0.1° |
C06 | C05 | C04 | H11 | 180.0° | 180.0° |
C06 | C05 | C04 | C03 | 0.0° | 0.0° |
C06 | C05 | C04 | H10 | 180.0° | 179.9° |
C26 | N19 | C20 | H1 | 57.1° | 66.2° |
C26 | N19 | C20 | H2 | 177.7° | 173.5° |
N19 | C26 | H5 | H6 | 120.1° | 120.4° |
N19 | C26 | C25 | H23 | 68.7° | 65.3° |
N19 | C26 | C25 | H24 | 172.1° | 174.6° |
C13 | C28 | N27 | C15 | 0.1° | 0.0° |
C13 | C28 | N27 | C03 | 180.0° | 179.9° |
C13 | C28 | C03 | C04 | 0.1° | 0.1° |
C13 | C28 | C03 | O02 | 179.9° | 180.0° |
N16 | C15 | N27 | C28 | 180.0° | 180.0° |
C15 | N27 | C28 | C03 | 179.9° | 179.9° |
N27 | C15 | N16 | H25 | 6.1° | 180.0° |
C05 | C04 | C03 | C28 | 0.1° | 0.1° |
C05 | C04 | C03 | H10 | 180.0° | 180.0° |
C05 | C04 | C03 | O02 | 180.0° | 180.0° |
N27 | C28 | C03 | C04 | 179.9° | 180.0° |
N27 | C28 | C03 | O02 | 0.0° | 0.0° |
C28 | C03 | C04 | O02 | 179.9° | 179.9° |
C28 | C03 | O02 | C01 | 142.1° | 180.0° |
C28 | C03 | C04 | H10 | 179.9° | 179.9° |
C04 | C03 | O02 | C01 | 37.9° | 0.1° |
C03 | C04 | C05 | H11 | 180.0° | 180.0° |
C03 | O02 | C01 | H7 | 180.0° | 180.0° |
C03 | O02 | C01 | H8 | 60.0° | 60.0° |
C03 | O02 | C01 | H9 | 60.0° | 60.0° |
O02 | C03 | C04 | H10 | 0.0° | 0.0° |
O02 | C01 | H7 | H8 | 120.0° | 120.0° |
O02 | C01 | H7 | H9 | 120.0° | 119.9° |
O02 | C01 | H8 | H9 | 120.0° | 120.0° |
H1 | C20 | C21 | H3 | 54.4° | 174.9° |
H1 | C20 | C21 | H4 | 173.5° | 54.8° |
H2 | C20 | C21 | H3 | 66.2° | 54.6° |
H2 | C20 | C21 | H4 | 52.9° | 65.6° |
H5 | C26 | C25 | H23 | 51.2° | 54.4° |
H5 | C26 | C25 | H24 | 68.0° | 65.7° |
H6 | C26 | C25 | H23 | 171.3° | 174.8° |
H6 | C26 | C25 | H24 | 52.1° | 54.7° |
H7 | C01 | H8 | H9 | 120.0° | 120.0° |
H10 | C04 | C05 | H11 | 0.0° | 0.0° |
H12 | C08 | C09 | H14 | 67.8° | 177.0° |
H12 | C08 | C09 | H15 | 51.6° | 57.0° |
H13 | C08 | C09 | H14 | 51.1° | 56.9° |
H13 | C08 | C09 | H15 | 170.5° | 63.2° |
H16 | C11 | C12 | H18 | 67.7° | 63.3° |
H16 | C11 | C12 | H19 | 51.3° | 56.9° |
H17 | C11 | C12 | H18 | 51.7° | 56.8° |
H17 | C11 | C12 | H19 | 170.7° | 177.0° |
H20 | C23 | H21 | H22 | 120.0° | 120.0° |