8M6
Bonds
First atom | Second atom | Bond order type | Distance (experimental model) | Distance (ideal model) | Properties |
C21 | C22 | doub | 1.38Å | 1.38Å | Aromatic |
C21 | N5 | sing | 1.32Å | 1.34Å | Aromatic |
C22 | C23 | sing | 1.39Å | 1.38Å | Aromatic |
N5 | C20 | doub | 1.32Å | 1.35Å | Aromatic |
O3 | C18 | doub | 1.21Å | 1.22Å | |
C23 | C19 | doub | 1.39Å | 1.40Å | Aromatic |
C20 | C19 | sing | 1.39Å | 1.43Å | Aromatic |
C20 | C24 | sing | 1.51Å | 1.50Å | |
C19 | N4 | sing | 1.40Å | 1.42Å | |
C18 | N4 | sing | 1.35Å | 1.35Å | |
C18 | C17 | sing | 1.51Å | 1.50Å | |
C15 | C16 | sing | 1.41Å | 1.41Å | Aromatic |
C15 | C14 | doub | 1.35Å | 1.37Å | Aromatic |
C16 | C13 | doub | 1.34Å | 1.34Å | Aromatic |
S2 | C17 | sing | 1.81Å | 1.80Å | |
S2 | C1 | sing | 1.76Å | 1.76Å | |
C14 | O2 | sing | 1.34Å | 1.35Å | Aromatic |
C13 | O2 | sing | 1.34Å | 1.37Å | Aromatic |
C13 | C12 | sing | 1.51Å | 1.49Å | |
C1 | N1 | doub | 1.32Å | 1.29Å | |
C1 | N2 | sing | 1.36Å | 1.39Å | |
N1 | C2 | sing | 1.35Å | 1.35Å | |
C12 | N2 | sing | 1.47Å | 1.47Å | |
N2 | C4 | sing | 1.36Å | 1.41Å | |
C2 | S1 | sing | 1.75Å | 1.72Å | Aromatic |
C2 | C3 | doub | 1.40Å | 1.37Å | Aromatic |
S1 | C5 | sing | 1.76Å | 1.73Å | Aromatic |
C4 | C3 | sing | 1.43Å | 1.41Å | |
C4 | O4 | doub | 1.22Å | 1.23Å | |
C3 | C6 | sing | 1.45Å | 1.44Å | Aromatic |
C5 | C6 | doub | 1.34Å | 1.36Å | Aromatic |
C5 | C7 | sing | 1.52Å | 1.48Å | |
C6 | C9 | sing | 1.52Å | 1.49Å | |
C7 | N3 | sing | 1.47Å | 1.44Å | |
C9 | C8 | sing | 1.53Å | 1.50Å | |
O1 | C10 | doub | 1.21Å | 1.25Å | |
N3 | C10 | sing | 1.35Å | 1.33Å | |
N3 | C8 | sing | 1.47Å | 1.46Å | |
C10 | C11 | sing | 1.51Å | 1.48Å | |
C7 | H1 | sing | 1.09Å | 1.10Å | |
C7 | H2 | sing | 1.09Å | 1.10Å | |
C8 | H3 | sing | 1.09Å | 1.10Å | |
C8 | H4 | sing | 1.09Å | 1.10Å | |
C15 | H5 | sing | 1.08Å | 1.08Å | |
C17 | H6 | sing | 1.09Å | 1.10Å | |
C17 | H7 | sing | 1.09Å | 1.10Å | |
C21 | H8 | sing | 1.08Å | 1.08Å | |
C22 | H9 | sing | 1.08Å | 1.08Å | |
C24 | H10 | sing | 1.09Å | 1.10Å | |
C24 | H11 | sing | 1.09Å | 1.10Å | |
C24 | H12 | sing | 1.09Å | 1.10Å | |
C9 | H13 | sing | 1.09Å | 1.10Å | |
C9 | H14 | sing | 1.09Å | 1.10Å | |
C11 | H15 | sing | 1.09Å | 1.10Å | |
C11 | H16 | sing | 1.09Å | 1.10Å | |
C11 | H17 | sing | 1.09Å | 1.10Å | |
C12 | H18 | sing | 1.09Å | 1.10Å | |
C12 | H19 | sing | 1.09Å | 1.10Å | |
C14 | H20 | sing | 1.08Å | 1.08Å | |
C16 | H21 | sing | 1.08Å | 1.08Å | |
N4 | H22 | sing | 0.97Å | 1.00Å | |
C23 | H23 | sing | 1.08Å | 1.08Å |
Angles
First atom | Second atom | Third atom | Angle (experimental model) | Angle (ideal model) |
C22 | C21 | N5 | 123.8° | 120.9° |
C21 | C22 | C23 | 118.8° | 119.3° |
C22 | C21 | H8 | 118.1° | 119.5° |
C21 | C22 | H9 | 120.6° | 120.4° |
C21 | N5 | C20 | 118.8° | 121.8° |
N5 | C21 | H8 | 118.1° | 119.6° |
C22 | C23 | C19 | 119.3° | 118.3° |
C23 | C22 | H9 | 120.6° | 120.3° |
C22 | C23 | H23 | 120.3° | 120.9° |
N5 | C20 | C19 | 120.9° | 120.7° |
N5 | C20 | C24 | 116.7° | 119.7° |
O3 | C18 | N4 | 123.9° | 120.0° |
O3 | C18 | C17 | 120.7° | 120.0° |
C23 | C19 | C20 | 118.4° | 119.0° |
C23 | C19 | N4 | 122.2° | 120.5° |
C19 | C23 | H23 | 120.3° | 120.8° |
C19 | C20 | C24 | 122.4° | 119.7° |
C20 | C19 | N4 | 119.4° | 120.5° |
C20 | C24 | H10 | 109.5° | 109.5° |
C20 | C24 | H11 | 109.5° | 109.5° |
C20 | C24 | H12 | 109.5° | 109.5° |
C19 | N4 | C18 | 124.9° | 120.0° |
C19 | N4 | H22 | 117.5° | 120.0° |
N4 | C18 | C17 | 115.3° | 120.0° |
C18 | N4 | H22 | 117.6° | 120.0° |
C18 | C17 | S2 | 104.4° | 109.5° |
C18 | C17 | H6 | 110.7° | 109.5° |
C18 | C17 | H7 | 110.7° | 109.5° |
C16 | C15 | C14 | 105.8° | 106.8° |
C15 | C16 | C13 | 107.7° | 106.9° |
C16 | C15 | H5 | 127.1° | 126.6° |
C15 | C16 | H21 | 126.2° | 126.6° |
C15 | C14 | O2 | 109.8° | 108.4° |
C14 | C15 | H5 | 127.1° | 126.5° |
C15 | C14 | H20 | 125.1° | 125.8° |
C16 | C13 | O2 | 109.2° | 108.4° |
C16 | C13 | C12 | 133.1° | 125.8° |
C13 | C16 | H21 | 126.1° | 126.6° |
C17 | S2 | C1 | 104.4° | 100.0° |
S2 | C17 | H6 | 110.7° | 109.4° |
S2 | C17 | H7 | 110.7° | 109.5° |
S2 | C1 | N1 | 117.4° | 118.3° |
S2 | C1 | N2 | 119.8° | 118.3° |
C14 | O2 | C13 | 107.4° | 109.5° |
O2 | C14 | H20 | 125.1° | 125.8° |
O2 | C13 | C12 | 117.6° | 125.8° |
C13 | C12 | N2 | 100.7° | 109.4° |
C13 | C12 | H18 | 111.6° | 109.5° |
C13 | C12 | H19 | 111.6° | 109.5° |
N1 | C1 | N2 | 122.8° | 123.4° |
C1 | N1 | C2 | 116.5° | 117.9° |
C1 | N2 | C12 | 122.0° | 119.0° |
C1 | N2 | C4 | 121.3° | 122.0° |
N1 | C2 | S1 | 121.5° | 128.8° |
N1 | C2 | C3 | 126.4° | 121.6° |
C12 | N2 | C4 | 116.6° | 119.0° |
N2 | C12 | H18 | 111.6° | 109.5° |
N2 | C12 | H19 | 111.6° | 109.5° |
N2 | C4 | C3 | 115.4° | 115.6° |
N2 | C4 | O4 | 120.0° | 122.2° |
S1 | C2 | C3 | 112.0° | 109.7° |
C2 | S1 | C5 | 90.9° | 92.3° |
C2 | C3 | C4 | 117.5° | 119.4° |
C2 | C3 | C6 | 112.3° | 113.0° |
S1 | C5 | C6 | 112.5° | 111.5° |
S1 | C5 | C7 | 121.8° | 124.3° |
C3 | C4 | O4 | 124.4° | 122.2° |
C4 | C3 | C6 | 129.9° | 127.5° |
C3 | C6 | C5 | 111.5° | 113.4° |
C3 | C6 | C9 | 128.0° | 123.1° |
C6 | C5 | C7 | 125.7° | 124.2° |
C5 | C6 | C9 | 120.2° | 123.4° |
C5 | C7 | N3 | 106.0° | 107.8° |
C5 | C7 | H1 | 110.3° | 109.8° |
C5 | C7 | H2 | 110.3° | 109.8° |
C6 | C9 | C8 | 109.2° | 109.3° |
C6 | C9 | H13 | 109.5° | 109.5° |
C6 | C9 | H14 | 109.5° | 109.5° |
C7 | N3 | C10 | 118.2° | 121.1° |
C7 | N3 | C8 | 113.3° | 117.7° |
N3 | C7 | H1 | 110.3° | 109.8° |
N3 | C7 | H2 | 110.3° | 109.8° |
C9 | C8 | N3 | 106.7° | 108.7° |
C9 | C8 | H3 | 110.2° | 109.6° |
C9 | C8 | H4 | 110.2° | 109.7° |
C8 | C9 | H13 | 109.5° | 109.5° |
C8 | C9 | H14 | 109.5° | 109.5° |
O1 | C10 | N3 | 121.0° | 120.0° |
O1 | C10 | C11 | 120.8° | 120.0° |
C10 | N3 | C8 | 128.3° | 121.2° |
N3 | C10 | C11 | 117.9° | 120.0° |
N3 | C8 | H3 | 110.1° | 109.6° |
N3 | C8 | H4 | 110.1° | 109.6° |
C10 | C11 | H15 | 109.5° | 109.5° |
C10 | C11 | H16 | 109.5° | 109.4° |
C10 | C11 | H17 | 109.5° | 109.5° |
H1 | C7 | H2 | 109.5° | 109.9° |
H3 | C8 | H4 | 109.5° | 109.6° |
H6 | C17 | H7 | 109.5° | 109.4° |
H10 | C24 | H11 | 109.5° | 109.4° |
H10 | C24 | H12 | 109.5° | 109.5° |
H11 | C24 | H12 | 109.4° | 109.5° |
H13 | C9 | H14 | 109.5° | 109.5° |
H15 | C11 | H16 | 109.5° | 109.5° |
H15 | C11 | H17 | 109.4° | 109.5° |
H16 | C11 | H17 | 109.4° | 109.5° |
H18 | C12 | H19 | 109.5° | 109.5° |
Dihedrals
First atom | Second atom | Third atom | Fourth atom | Torsion (experimental model) | Torsion (ideal model) |
C22 | C21 | N5 | H8 | 180.0° | 179.1° |
C21 | C22 | C23 | H9 | 180.0° | 179.1° |
C22 | C21 | N5 | C20 | 0.0° | 0.6° |
C21 | C22 | C23 | C19 | 0.7° | 0.5° |
C21 | C22 | C23 | H23 | 179.2° | 180.0° |
N5 | C21 | C22 | C23 | 0.1° | 0.8° |
C21 | N5 | C20 | C19 | 0.6° | 0.0° |
C21 | N5 | C20 | C24 | 179.8° | 179.7° |
N5 | C21 | C22 | H9 | 179.9° | 180.0° |
C22 | C23 | C19 | H23 | 180.0° | 179.5° |
C22 | C23 | C19 | C20 | 1.3° | 0.0° |
C22 | C23 | C19 | N4 | 178.7° | 180.0° |
C23 | C22 | C21 | H8 | 180.0° | 180.0° |
N5 | C20 | C19 | C23 | 1.3° | 0.3° |
N5 | C20 | C19 | C24 | 179.5° | 179.7° |
N5 | C20 | C19 | N4 | 178.7° | 179.7° |
C20 | N5 | C21 | H8 | 180.0° | 179.7° |
N5 | C20 | C24 | H10 | 0.0° | 90.3° |
N5 | C20 | C24 | H11 | 120.0° | 29.7° |
N5 | C20 | C24 | H12 | 120.0° | 149.7° |
O3 | C18 | N4 | C19 | 17.6° | 5.6° |
O3 | C18 | N4 | C17 | 179.8° | 180.0° |
O3 | C18 | C17 | S2 | 21.9° | 0.0° |
O3 | C18 | C17 | H6 | 97.3° | 120.0° |
O3 | C18 | C17 | H7 | 141.1° | 120.0° |
O3 | C18 | N4 | H22 | 162.4° | 174.4° |
C23 | C19 | C20 | N4 | 177.4° | 180.0° |
C23 | C19 | C20 | C24 | 179.2° | 180.0° |
C23 | C19 | N4 | C18 | 112.1° | 24.6° |
C19 | C23 | C22 | H9 | 179.2° | 179.7° |
C23 | C19 | N4 | H22 | 67.9° | 155.4° |
C20 | C19 | N4 | C18 | 65.2° | 155.4° |
C19 | C20 | C24 | H10 | 179.5° | 90.0° |
C19 | C20 | C24 | H11 | 60.4° | 150.0° |
C19 | C20 | C24 | H12 | 59.5° | 30.0° |
C20 | C19 | N4 | H22 | 114.8° | 24.6° |
C20 | C19 | C23 | H23 | 178.7° | 179.5° |
C24 | C20 | C19 | N4 | 1.8° | 0.0° |
C20 | C24 | H10 | H11 | 120.0° | 120.0° |
C20 | C24 | H10 | H12 | 120.0° | 120.0° |
C20 | C24 | H11 | H12 | 120.0° | 120.0° |
C19 | N4 | C18 | H22 | 180.0° | 180.0° |
C19 | N4 | C18 | C17 | 162.6° | 174.4° |
N4 | C19 | C23 | H23 | 1.3° | 0.5° |
N4 | C18 | C17 | S2 | 157.9° | 180.0° |
N4 | C18 | C17 | H6 | 82.9° | 60.0° |
N4 | C18 | C17 | H7 | 38.7° | 60.0° |
C18 | C17 | S2 | H6 | 119.2° | 120.0° |
C18 | C17 | S2 | H7 | 119.2° | 120.1° |
C18 | C17 | S2 | C1 | 93.0° | 180.0° |
C18 | C17 | H6 | H7 | 122.3° | 120.1° |
C17 | C18 | N4 | H22 | 17.4° | 5.6° |
C16 | C15 | C14 | H5 | 180.0° | 179.5° |
C15 | C16 | C13 | H21 | 180.0° | 179.6° |
C16 | C15 | C14 | O2 | 1.2° | 0.3° |
C15 | C16 | C13 | O2 | 2.2° | 0.4° |
C15 | C16 | C13 | C12 | 177.6° | 179.8° |
C16 | C15 | C14 | H20 | 178.8° | 179.9° |
C14 | C15 | C16 | C13 | 2.1° | 0.4° |
C15 | C14 | O2 | H20 | 180.0° | 179.8° |
C15 | C14 | O2 | C13 | 0.1° | 0.0° |
C14 | C15 | C16 | H21 | 177.9° | 180.0° |
C16 | C13 | O2 | C14 | 1.4° | 0.3° |
C16 | C13 | O2 | C12 | 176.2° | 179.8° |
C16 | C13 | C12 | N2 | 78.1° | 89.7° |
C13 | C16 | C15 | H5 | 177.9° | 180.0° |
C16 | C13 | C12 | H18 | 163.4° | 150.2° |
C16 | C13 | C12 | H19 | 40.5° | 30.2° |
C17 | S2 | C1 | N1 | 57.7° | 0.0° |
C17 | S2 | C1 | N2 | 123.8° | 180.0° |
S2 | C17 | H6 | H7 | 122.4° | 120.0° |
S2 | C1 | N1 | N2 | 178.4° | 180.0° |
S2 | C1 | N1 | C2 | 178.5° | 180.0° |
S2 | C1 | N2 | C12 | 3.8° | 0.1° |
S2 | C1 | N2 | C4 | 179.2° | 179.9° |
C1 | S2 | C17 | H6 | 147.8° | 60.0° |
C1 | S2 | C17 | H7 | 26.2° | 60.0° |
C14 | O2 | C13 | C12 | 177.7° | 179.9° |
O2 | C14 | C15 | H5 | 178.8° | 179.8° |
O2 | C13 | C12 | N2 | 97.0° | 90.0° |
O2 | C13 | C12 | H18 | 21.5° | 30.0° |
O2 | C13 | C12 | H19 | 144.4° | 150.0° |
C13 | O2 | C14 | H20 | 179.9° | 179.8° |
O2 | C13 | C16 | H21 | 177.8° | 180.0° |
C13 | C12 | N2 | C1 | 92.4° | 90.0° |
C13 | C12 | N2 | H18 | 118.6° | 120.0° |
C13 | C12 | N2 | H19 | 118.6° | 120.0° |
C13 | C12 | N2 | C4 | 84.7° | 90.0° |
C13 | C12 | H18 | H19 | 124.1° | 120.0° |
C12 | C13 | C16 | H21 | 2.4° | 0.2° |
N1 | C1 | N2 | C12 | 174.6° | 180.0° |
N1 | C1 | N2 | C4 | 2.4° | 0.1° |
C1 | N1 | C2 | S1 | 179.7° | 179.9° |
C1 | N1 | C2 | C3 | 4.2° | 0.1° |
N2 | C1 | N1 | C2 | 3.0° | 0.0° |
C1 | N2 | C12 | C4 | 177.1° | 180.0° |
C1 | N2 | C4 | C3 | 2.3° | 0.0° |
C1 | N2 | C4 | O4 | 178.3° | 180.0° |
C1 | N2 | C12 | H18 | 149.0° | 30.0° |
C1 | N2 | C12 | H19 | 26.2° | 150.0° |
N1 | C2 | S1 | C3 | 176.1° | 180.0° |
N1 | C2 | S1 | C5 | 176.5° | 180.0° |
N1 | C2 | C3 | C4 | 4.4° | 0.2° |
N1 | C2 | C3 | C6 | 179.6° | 179.7° |
C12 | N2 | C4 | C3 | 174.8° | 180.0° |
C12 | N2 | C4 | O4 | 1.2° | 0.0° |
N2 | C12 | H18 | H19 | 124.1° | 120.0° |
N2 | C4 | C3 | C2 | 3.1° | 0.1° |
N2 | C4 | C3 | O4 | 175.8° | 180.0° |
N2 | C4 | C3 | C6 | 177.4° | 179.8° |
C4 | N2 | C12 | H18 | 33.8° | 150.0° |
C4 | N2 | C12 | H19 | 156.7° | 30.0° |
S1 | C2 | C3 | C4 | 179.8° | 179.8° |
S1 | C2 | C3 | C6 | 4.5° | 0.2° |
C2 | S1 | C5 | C6 | 8.6° | 0.2° |
C2 | S1 | C5 | C7 | 173.3° | 179.9° |
C3 | C2 | S1 | C5 | 7.4° | 0.0° |
C2 | C3 | C4 | C6 | 174.3° | 179.9° |
C2 | C3 | C4 | O4 | 178.9° | 179.9° |
C2 | C3 | C6 | C5 | 2.0° | 0.4° |
C2 | C3 | C6 | C9 | 175.8° | 179.5° |
S1 | C5 | C6 | C3 | 7.6° | 0.4° |
S1 | C5 | C6 | C7 | 178.0° | 179.9° |
S1 | C5 | C6 | C9 | 178.1° | 179.5° |
S1 | C5 | C7 | N3 | 162.8° | 169.3° |
S1 | C5 | C7 | H1 | 77.8° | 49.7° |
S1 | C5 | C7 | H2 | 43.3° | 71.1° |
C4 | C3 | C6 | C5 | 172.6° | 179.7° |
C4 | C3 | C6 | C9 | 1.2° | 0.4° |
O4 | C4 | C3 | C6 | 6.8° | 0.2° |
C3 | C6 | C5 | C9 | 174.3° | 180.0° |
C3 | C6 | C5 | C7 | 174.4° | 179.7° |
C3 | C6 | C9 | C8 | 154.6° | 161.0° |
C3 | C6 | C9 | H13 | 85.4° | 79.0° |
C3 | C6 | C9 | H14 | 34.7° | 41.1° |
C6 | C5 | C7 | N3 | 15.1° | 10.6° |
C5 | C6 | C9 | C8 | 18.6° | 19.0° |
C6 | C5 | C7 | H1 | 104.4° | 130.2° |
C6 | C5 | C7 | H2 | 134.6° | 109.0° |
C5 | C6 | C9 | H13 | 101.3° | 100.9° |
C5 | C6 | C9 | H14 | 138.6° | 139.0° |
C7 | C5 | C6 | C9 | 0.1° | 0.4° |
C5 | C7 | N3 | H1 | 119.4° | 119.6° |
C5 | C7 | N3 | H2 | 119.5° | 119.6° |
C5 | C7 | N3 | C10 | 124.5° | 136.1° |
C5 | C7 | N3 | C8 | 52.2° | 43.8° |
C5 | C7 | H1 | H2 | 121.6° | 120.8° |
C6 | C9 | C8 | H13 | 119.9° | 120.0° |
C6 | C9 | C8 | H14 | 119.9° | 120.0° |
C6 | C9 | C8 | N3 | 51.5° | 46.9° |
C6 | C9 | C8 | H3 | 171.0° | 72.9° |
C6 | C9 | C8 | H4 | 68.1° | 166.7° |
C6 | C9 | H13 | H14 | 120.1° | 120.1° |
C7 | N3 | C8 | C9 | 74.2° | 64.8° |
C7 | N3 | C10 | O1 | 3.9° | 180.0° |
C7 | N3 | C10 | C8 | 176.1° | 180.0° |
C7 | N3 | C10 | C11 | 176.6° | 0.0° |
N3 | C7 | H1 | H2 | 121.6° | 120.8° |
C7 | N3 | C8 | H3 | 166.2° | 55.0° |
C7 | N3 | C8 | H4 | 45.3° | 175.3° |
C9 | C8 | N3 | C10 | 102.0° | 115.2° |
C9 | C8 | N3 | H3 | 119.6° | 119.8° |
C9 | C8 | N3 | H4 | 119.5° | 119.9° |
C9 | C8 | H3 | H4 | 121.3° | 120.4° |
C8 | C9 | H13 | H14 | 120.1° | 120.0° |
O1 | C10 | N3 | C11 | 172.7° | 179.9° |
O1 | C10 | N3 | C8 | 180.0° | 0.1° |
O1 | C10 | C11 | H15 | 0.0° | 120.0° |
O1 | C10 | C11 | H16 | 120.0° | 0.0° |
O1 | C10 | C11 | H17 | 120.0° | 119.9° |
C10 | N3 | C7 | H1 | 116.1° | 16.6° |
C10 | N3 | C7 | H2 | 5.0° | 104.3° |
C10 | N3 | C8 | H3 | 17.6° | 125.0° |
C10 | N3 | C8 | H4 | 138.4° | 4.7° |
N3 | C10 | C11 | H15 | 172.7° | 60.0° |
N3 | C10 | C11 | H16 | 67.3° | 179.9° |
N3 | C10 | C11 | H17 | 52.7° | 60.0° |
C8 | N3 | C10 | C11 | 7.3° | 180.0° |
C8 | N3 | C7 | H1 | 67.3° | 163.4° |
C8 | N3 | C7 | H2 | 171.7° | 75.7° |
N3 | C8 | H3 | H4 | 121.3° | 120.3° |
N3 | C8 | C9 | H13 | 68.5° | 73.1° |
N3 | C8 | C9 | H14 | 171.4° | 166.9° |
C10 | C11 | H15 | H16 | 120.0° | 120.0° |
C10 | C11 | H15 | H17 | 120.0° | 120.0° |
C10 | C11 | H16 | H17 | 120.0° | 120.0° |
H3 | C8 | C9 | H13 | 51.1° | 167.1° |
H3 | C8 | C9 | H14 | 69.0° | 47.0° |
H4 | C8 | C9 | H13 | 172.0° | 46.8° |
H4 | C8 | C9 | H14 | 51.9° | 73.3° |
H5 | C15 | C14 | H20 | 1.3° | 0.4° |
H5 | C15 | C16 | H21 | 2.1° | 0.5° |
H8 | C21 | C22 | H9 | 0.0° | 0.9° |
H9 | C22 | C23 | H23 | 0.8° | 0.8° |
H10 | C24 | H11 | H12 | 120.0° | 120.0° |
H15 | C11 | H16 | H17 | 120.0° | 120.0° |