2PO
Bonds
| First atom | Second atom | Bond order type | Distance (experimental model) | Distance (ideal model) | Properties |
| P | O1P | sing | 1.53Å | 1.49Å | |
| P | O2P | sing | 1.53Å | 1.49Å | |
| P | O3P | doub | 1.53Å | 1.59Å | |
| P | HP | sing | 1.41Å | 1.42Å |
Angles
| First atom | Second atom | Third atom | Angle (experimental model) | Angle (ideal model) |
| O1P | P | O2P | 119.7° | 113.8° |
| O1P | P | O3P | 105.0° | 113.8° |
| O1P | P | HP | 105.3° | 104.6° |
| O2P | P | O3P | 108.3° | 113.9° |
| O2P | P | HP | 101.8° | 104.6° |
| O3P | P | HP | 117.3° | 104.7° |
Dihedrals
| First atom | Second atom | Third atom | Fourth atom | Torsion (experimental model) | Torsion (ideal model) |
| O1P | P | O2P | O3P | 120.2° | 132.7° |
| O1P | P | O2P | HP | 115.5° | 113.6° |
| O1P | P | O3P | HP | 116.6° | 113.6° |
| O2P | P | O3P | HP | 114.5° | 113.7° |
