5OEF

Active semisynthetic [FeFe]-hydrogenase CpI with aza-diselenato-bridged [2Fe] cofactor

Summary for 5OEF

• Entry DOI: 10.2210/pdb5oef/pdb
• Descriptor: Iron hydrogenase 1, dicarbonyl[bis(cyanide-kappaC)]-mu-(iminodimethaneselenato- 1kappaS:2kappaS)-mu-(oxomethylidene)diiron(2+), IRON/SULFUR CLUSTER, ... (6 entities in total)
• Functional Keywords: hydrogenase, h-cluster, oxidoreductase
• Biological source: Clostridium pasteurianum
• Total number of polymer chains: 2
• Total formula weight: 134406.59

Authors

Kertess, L.,Esselborn, J.,Happe, T.,Hofmann, E. (deposition date: 2017-07-07, release date: 2017-11-29, Last modification date: 2024-01-17)

• Primary citation: Kertess, L.,Wittkamp, F.,Sommer, C.,Esselborn, J.,Rudiger, O.,Reijerse, E.J.,Hofmann, E.,Lubitz, W.,Winkler, M.,Happe, T.,Apfel, U.P.; Chalcogenide substitution in the [2Fe] cluster of [FeFe]-hydrogenases conserves high enzymatic activity.; Dalton Trans, 46:16947-16958, 2017; PubMed: 29177350; DOI: 10.1039/c7dt03785f

Experimental method

X-RAY DIFFRACTION (2.05 Å)