2ZG7

Crystal Structure of Pd(allyl)/apo-Fr

Summary for 2ZG7

Entry DOI	10.2210/pdb2zg7/pdb
Related	2ZG8 2ZG9
Descriptor	Ferritin light chain, CADMIUM ION, SULFATE ION, ... (6 entities in total)
Functional Keywords	iron storage protein, light chain apoferritin, artificial metalloprotein, metal binding protein
Biological source	Equus caballus (Horse)
Total number of polymer chains	1
Total formula weight	21455.60
Authors	Abe, S.,Niemeyer, J.,Abe, M.,Ueno, T.,Hikage, T.,Erker, G.,Watanabe, Y. (deposition date: 2008-01-18, release date: 2008-08-26, Last modification date: 2023-11-01)
Primary citation	Abe, S.,Niemeyer, J.,Abe, M.,Takezawa, Y.,Ueno, T.,Hikage, T.,Erker, G.,Watanabe, Y. Control of the coordination structure of organometallic palladium complexes in an apo-ferritin cage. J.Am.Chem.Soc., 130:10512-10514, 2008 Cited by PubMed Abstract: We report the preparation of organometallic Pd(allyl) dinuclear complexes in protein cages of apo-Fr by reactions with [Pd(allyl)Cl]2 (allyl = eta3-C3H5). One of the dinuclear complexes is converted to a trinuclear complex by replacing a Pd-coordinated His residue to an Ala residue. These results suggest that multinuclear metal complexes with various coordination structures could be prepared by the deletion or introduction of His, Cys, and Glu at appropriate positions on protein surface. PubMed: 18636721 DOI: 10.1021/ja802463a PDB entries with the same primary citation
Experimental method	X-RAY DIFFRACTION (1.7 Å)

Structure validation