7QHR

Unexpected imidazole coordination to dirhodium tetraacetate complex in a protein environment: insights from X-ray crystallography and quantum chemistry

7QHR の概要

• エントリーDOI: 10.2210/pdb7qhr/pdb
• 分子名称: Ribonuclease pancreatic, tri-(mi2-acetato-(O, O')-diaqua-dirhodium(II, II), octaaqua-dirhodium (II, II) fragment, ... (6 entities in total)
• 機能のキーワード: in-crystallo reactivity, protein metalation, dirhodium tetraacetate, hydrolase
• 由来する生物種: Bos taurus (cattle)
• タンパク質・核酸の鎖数: 2
• 化学式量合計: 29313.36

構造登録者

Loreto, D.,Merlino, A. (登録日: 2021-12-13, 公開日: 2022-06-08, 最終更新日: 2024-01-31)

• 主引用文献: Loreto, D.,Fasulo, F.,Munoz-Garcia, A.B.,Pavone, M.,Merlino, A.; Unexpected Imidazole Coordination to the Dirhodium Center in a Protein Environment: Insights from X-ray Crystallography and Quantum Chemistry.; Inorg.Chem., 61:8402-8405, 2022; PubMed: 35609175; DOI: 10.1021/acs.inorgchem.2c01370

実験手法

X-RAY DIFFRACTION (1.4 Å)