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Structure paper

TitleIntramolecular Coupling and Nucleobase Transfer - How Cytochrome P450 Enzymes GymBx Establish Their Chemoselectivity
Journal, issue, pagesChemcatchem, Vol. 16, Year 2024
Publish dateAug 15, 2023 (structure data deposition date)
AuthorsFreytag, J. / Martin, A. / Muller, J.C. / Kelm, T. / Stehle, T. / Li, S.M. / Zocher, G.
External linksChemcatchem / Search PubMed
MethodsX-ray diffraction
Resolution1.81 - 1.96 Å
Structure data

PDB-8q6x:
Crystal structure of Cytochrome P450 GymB5 from Streptomyces katrae
Method: X-RAY DIFFRACTION / Resolution: 1.91 Å

PDB-8q6y:
Crystal structure of Cytochrome P450 GymB5 from Streptomyces katrae in complex with cYY and Hypoxanthine
Method: X-RAY DIFFRACTION / Resolution: 1.81 Å

PDB-8q6z:
Crystal structure of Cytochrome P450 GymB1 from Streptomyces flavidovirens
Method: X-RAY DIFFRACTION / Resolution: 1.96 Å

Chemicals

ChemComp-HEM:
PROTOPORPHYRIN IX CONTAINING FE

ChemComp-HOH:
WATER

ChemComp-YTT:
(3S,6S)-3,6-bis(4-hydroxybenzyl)piperazine-2,5-dione

ChemComp-HPA:
HYPOXANTHINE

ChemComp-EDO:
1,2-ETHANEDIOL

ChemComp-GOL:
GLYCEROL

Source
  • streptomyces katrae (bacteria)
  • streptomyces flavidovirens dsm 40150 (bacteria)
KeywordsOXIDOREDUCTASE / Nucleobase transferase / Cytochrome P450 / Mycocyclosin synthetase / prism-like fold

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