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TitleDiscovery and Biosynthesis of Cihanmycins Reveal Cytochrome P450-Catalyzed Intramolecular C-O Phenol Coupling Reactions.
Journal, issue, pagesJ. Am. Chem. Soc., Year 2024
Publish dateAug 30, 2023 (structure data deposition date)
AuthorsFang, C. / Zhang, L. / Wang, Y. / Xiong, W. / Yan, Z. / Zhang, W. / Zhang, Q. / Wang, B. / Zhu, Y. / Zhang, C.
External linksJ. Am. Chem. Soc. / PubMed:38842938
MethodsX-ray diffraction
Resolution2.2 - 3.25 Å
Structure data

PDB-8w6z:
Substrate-bound crystal structure of a P450 enzyme DmlH that catalyze intramolecular phenol coupling in the biosynthesis of cihanmycins
Method: X-RAY DIFFRACTION / Resolution: 2.2 Å

PDB-8w72:
Crystal structure of a P450 enzyme DmlH that catalyze intramolecular phenol coupling in the biosynthesis of cihanmycins
Method: X-RAY DIFFRACTION / Resolution: 3.25 Å

Chemicals

ChemComp-HEM:
PROTOPORPHYRIN IX CONTAINING FE


ChemComp, No image

ChemComp-R8L:
Unknown entry

ChemComp-HOH:
WATER

Source
  • streptomyces sp. dm14 (bacteria)
KeywordsBIOSYNTHETIC PROTEIN / P450 enzyme / intramolecular phenol coupling / cihanmycins

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