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TitleCatalytic iron-carbene intermediate revealed in a cytochromeccarbene transferase.
Journal, issue, pagesProc. Natl. Acad. Sci. U.S.A., Vol. 115, Page 7308-7313, Year 2018
Publish dateMar 26, 2018 (structure data deposition date)
AuthorsLewis, R.D. / Garcia-Borras, M. / Chalkley, M.J. / Buller, A.R. / Houk, K.N. / Kan, S.B.J. / Arnold, F.H.
External linksProc. Natl. Acad. Sci. U.S.A. / PubMed:29946033
MethodsX-ray diffraction
Resolution1.29 - 1.47 Å
Structure data

PDB-6cuk:
Engineered Cytochrome c from Rhodothermus marinus, Rma TDE
Method: X-RAY DIFFRACTION / Resolution: 1.47 Å

PDB-6cun:
Engineered Cytochrome c from Rhodothermus marinus (Rma TDE) bound to carbene intermediate (1-ethoxy-1-oxopropan-2-ylidene)
Method: X-RAY DIFFRACTION / Resolution: 1.29 Å

Chemicals

ChemComp-HEC:
HEME C

ChemComp-HOH:
WATER

ChemComp-CA1:
ETHYL PROPIONATE

Source
  • rhodothermus marinus (bacteria)
KeywordsLYASE / Carbene transferase / silicon-carbon bond

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