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Structure paper

TitleMechanistic studies of an unprecedented enzyme-catalysed 1,2-phosphono-migration reaction.
Journal, issue, pagesNature, Vol. 496, Page 114-118, Year 2013
Publish dateFeb 3, 2013 (structure data deposition date)
AuthorsChang, W.C. / Dey, M. / Liu, P. / Mansoorabadi, S.O. / Moon, S.J. / Zhao, Z.K. / Drennan, C.L. / Liu, H.W.
External linksNature / PubMed:23552950
MethodsX-ray diffraction
Resolution2.72 - 2.8 Å
Structure data

PDB-4j1w:
Crystal Structure of Fe(II)-HppE with alternative substrate (R)-1-HPP
Method: X-RAY DIFFRACTION / Resolution: 2.72 Å

PDB-4j1x:
Crystal Structure of Fe(II)-HppE with alternative substrate (S)-1-HPP
Method: X-RAY DIFFRACTION / Resolution: 2.8 Å

Chemicals

ChemComp-FE2:
Unknown entry

ChemComp-FFQ:
[(1R)-1-hydroxypropyl]phosphonic acid / antibiotic*YM

ChemComp-GOL:
GLYCEROL

ChemComp-HOH:
WATER

ChemComp-1JJ:
[(1S)-1-hydroxypropyl]phosphonic acid

Source
  • streptomyces wedmorensis (bacteria)
KeywordsMETAL BINDING PROTEIN / Hydroxypropylphosphonic acid epoxidase / 1 / 2-phosphono migration / mononuclear non-heme iron enzyme / cupin fold / phosphono migration / keto product

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