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Structure paper

TitleCoupling CO2 Reduction and Acetyl-CoA Formation: The Role of a CO Capturing Tunnel in Enzymatic Catalysis.
Journal, issue, pagesAngew. Chem. Int. Ed. Engl., Page e202405120-e202405120, Year 2024
Publish dateApr 13, 2022 (structure data deposition date)
AuthorsRuickoldt, J. / Jeoung, J.H. / Rudolph, M.A. / Lennartz, F. / Kreibich, J. / Schomacker, R. / Dobbek, H.
External linksAngew. Chem. Int. Ed. Engl. / PubMed:38743001
MethodsX-ray diffraction
Resolution2.066 - 2.6 Å
Structure data

PDB-7zkv:
F231A variant of the CODH/ACS complex of C. hydrogenoformans
Method: X-RAY DIFFRACTION / Resolution: 2.066 Å

PDB-8cja:
A225L/F231A variant of the CODH/ACS complex of C. hydrogenoformans
Method: X-RAY DIFFRACTION / Resolution: 2.1 Å

PDB-8cjb:
A268M variant of the CODH/ACS complex of C. hydrogenoformans
Method: X-RAY DIFFRACTION / Resolution: 2.5 Å

PDB-8cjc:
F515A variant of the CODH/ACS complex of C. hydrogenoformans
Method: X-RAY DIFFRACTION / Resolution: 2.22 Å

PDB-8cmw:
A225L variant of the CODH/ACS complex of C. hydrogenoformans
Method: X-RAY DIFFRACTION / Resolution: 2.6 Å

Chemicals

ChemComp-RQM:
Fe(3)-Ni(1)-S(4) cluster

ChemComp-SF4:
IRON/SULFUR CLUSTER

ChemComp-OH:
HYDROXIDE ION

ChemComp-MRD:
(4R)-2-METHYLPENTANE-2,4-DIOL / precipitant*YM

ChemComp-NI:
NICKEL (II) ION

ChemComp-ACT:
ACETATE ION

ChemComp-NA:
Unknown entry

ChemComp-HOH:
WATER

ChemComp-MPD:
(4S)-2-METHYL-2,4-PENTANEDIOL / precipitant*YM

ChemComp-FES:
FE2/S2 (INORGANIC) CLUSTER

Source
  • carboxydothermus hydrogenoformans z-2901 (bacteria)
  • synthetic construct (others)
KeywordsOXIDOREDUCTASE / CO2 reduction / acetyl-CoA synthesis / carbon monoxide / CODH / ACS

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