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TitleChemodivergent C(sp 3 )-H and C(sp 2 )-H Cyanomethylation Using Engineered Carbene Transferases.
Journal, issue, pagesNat Catal, Vol. 6, Page 152-160, Year 2023
Publish dateJul 22, 2022 (structure data deposition date)
AuthorsZhang, J. / Maggiolo, A.O. / Alfonzo, E. / Mao, R. / Porter, N.J. / Abney, N. / Arnold, F.H.
External linksNat Catal / PubMed:36875868
MethodsX-ray diffraction
Resolution1.87 Å
Structure data

PDB-8dsg:
P411-PFA carbene transferase
Method: X-RAY DIFFRACTION / Resolution: 1.87 Å

Chemicals

ChemComp-HEM:
PROTOPORPHYRIN IX CONTAINING FE

ChemComp-EDO:
1,2-ETHANEDIOL

ChemComp-SO4:
SULFATE ION

ChemComp-BTB:
2-[BIS-(2-HYDROXY-ETHYL)-AMINO]-2-HYDROXYMETHYL-PROPANE-1,3-DIOL / pH buffer*YM

ChemComp-HOH:
WATER

Source
  • priestia megaterium (bacteria)
KeywordsOXIDOREDUCTASE / cytochrome P450 / carbene transferase / cyanomethylase / fluoroalkylation

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