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Structure paper

TitleAn Unprecedented Cyclization Mechanism in the Biosynthesis of Carbazole Alkaloids in Streptomyces.
Journal, issue, pagesAngew. Chem. Int. Ed. Engl., Vol. 58, Page 13349-13353, Year 2019
Publish dateNov 5, 2018 (structure data deposition date)
AuthorsKobayashi, M. / Tomita, T. / Shin-Ya, K. / Nishiyama, M. / Kuzuyama, T.
External linksAngew. Chem. Int. Ed. Engl. / PubMed:31350791
MethodsX-ray diffraction
Resolution2.1 - 2.2 Å
Structure data

PDB-6ipv:
Crystal structure of CqsB2 from Streptomyces exfoliatus 2419-SVT2 (apo form)
Method: X-RAY DIFFRACTION / Resolution: 2.2 Å

PDB-6ipw:
Crystal structure of CqsB2 from Streptomyces exfoliatus in complex with the product, 1-(2-hydroxypropyl)-2-methyl-carbazole-3,4-dione
Method: X-RAY DIFFRACTION / Resolution: 2.1 Å

Chemicals

ChemComp-HOH:
WATER

ChemComp-AO6:
2-methyl-1-[(2R)-2-oxidanylpropyl]-9H-carbazole-3,4-dione

Source
  • streptomyces exfoliatus (bacteria)
KeywordsBIOSYNTHETIC PROTEIN / Carquinostatin A biosynthesis / polyketide aromatase/cyclase / Carbazole biosynthesis

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