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TitleEnantioselective, intermolecular benzylic C-H amination catalysed by an engineered iron-haem enzyme.
Journal, issue, pagesNat Chem, Vol. 9, Page 629-634, Year 2017
Publish dateDec 22, 2016 (structure data deposition date)
AuthorsPrier, C.K. / Zhang, R.K. / Buller, A.R. / Brinkmann-Chen, S. / Arnold, F.H.
External linksNat Chem / PubMed:28644476
MethodsX-ray diffraction
Resolution1.7 Å
Structure data

PDB-5ucw:
Cytochrome P411 P-4 A82L A78V F263L amination catalyst
Method: X-RAY DIFFRACTION / Resolution: 1.7 Å

Chemicals

ChemComp-HEM:
PROTOPORPHYRIN IX CONTAINING FE

ChemComp-HOH:
WATER

Source
  • bacillus megaterium (bacteria)
KeywordsOXIDOREDUCTASE / engineered / C-H functionalization / nitrene transfer / P411CHA

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