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Structure paper

TitleDirect visualization of a Fe(IV)-OH intermediate in a heme enzyme.
Journal, issue, pagesNat Commun, Vol. 7, Page 13445-13445, Year 2016
Publish dateMay 4, 2016 (structure data deposition date)
AuthorsKwon, H. / Basran, J. / Casadei, C.M. / Fielding, A.J. / Schrader, T.E. / Ostermann, A. / Devos, J.M. / Aller, P. / Blakeley, M.P. / Moody, P.C. / Raven, E.L.
External linksNat Commun / PubMed:27897163
MethodsX-ray diffraction / neutron diffraction
Resolution1.806 - 1.81 Å
Structure data

PDB-5jpr:
Neutron Structure of Compound II of Ascorbate Peroxidase
Method: X-RAY DIFFRACTION / NEUTRON DIFFRACTION / Resolution: 1.806 Å

PDB-5jqr:
The Structure of Ascorbate Peroxidase Compound II formed by reaction with m-CPBA
Method: X-RAY DIFFRACTION / Resolution: 1.81 Å

Chemicals

ChemComp-HEM:
PROTOPORPHYRIN IX CONTAINING FE

ChemComp-K:
Unknown entry

ChemComp-SO4:
SULFATE ION

ChemComp-DOD:
DEUTERATED WATER

ChemComp-HOH:
WATER

Source
  • glycine max (soybean)
KeywordsOXIDOREDUCTASE / Heme Peroxidase / Intermediate / Ferryle Heme / Compound II / Cryo-trapping / Intermediates / Ferryl / Multicrystal

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