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TitleStructure of Cytochrome P450 Pimd Suggests Epoxidation of the Polyene Macrolide Pimaricin Occurs Via a Hydroperoxoferric Intermediate.
Journal, issue, pagesChem. Biol., Vol. 17, Page 841-, Year 2010
Publish dateMar 23, 2010 (structure data deposition date)
AuthorsKells, P.M. / Ouellet, H. / Santos-Aberturas, J. / Aparicio, J.F. / Podust, L.M.
External linksChem. Biol. / PubMed:20797613
MethodsX-ray diffraction
Resolution1.95 - 2.1 Å
Structure data

PDB-2x9p:
X-ray structure of the substrate-free cytochrome P450 PimD - a polyene macrolide antibiotic pimaricin epoxidase
Method: X-RAY DIFFRACTION / Resolution: 2.1 Å

PDB-2xbk:
X-ray structure of the substrate-bound cytochrome P450 PimD - a polyene macrolide antibiotic pimaricin epoxidase
Method: X-RAY DIFFRACTION / Resolution: 1.95 Å

Chemicals

ChemComp-HEM:
PROTOPORPHYRIN IX CONTAINING FE

ChemComp-SO4:
SULFATE ION

ChemComp-HOH:
WATER

ChemComp-XBK:
4,5-DE-EPOXYPIMARICIN

Source
  • streptomyces natalensis (bacteria)
KeywordsOXIDOREDUCTASE / EPOXIDATION

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