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TitleStructural Characterization of the Fleeting Ferric Peroxo Species in Myoglobin: Experiment and Theory
Journal, issue, pagesJ. Am. Chem. Soc., Vol. 129, Page 13394-13395, Year 2007
Publish dateAug 8, 2007 (structure data deposition date)
AuthorsUnno, M. / Chen, H. / Kusama, S. / Shaik, S. / Ikeda-Saito, M.
External linksJ. Am. Chem. Soc. / PubMed:17929929
MethodsX-ray diffraction
Resolution1.2 - 1.25 Å
Structure data

PDB-2z6s:
Crystal structure of the oxy myoglobin free from X-ray-induced photoreduction
Method: X-RAY DIFFRACTION / Resolution: 1.25 Å

PDB-2z6t:
Crystal structure of the ferric peroxo myoglobin
Method: X-RAY DIFFRACTION / Resolution: 1.2 Å

Chemicals

ChemComp-SO4:
SULFATE ION

ChemComp-HEM:
PROTOPORPHYRIN IX CONTAINING FE

ChemComp-OXY:
OXYGEN MOLECULE

ChemComp-HOH:
WATER

ChemComp-PER:
PEROXIDE ION

Source
  • physeter catodon (sperm whale)
KeywordsOXYGEN BINDING / heme / oxygen transport / Microspectrophotometer / X-ray-induced-photoreduction / Iron / Metal-binding / Muscle protein / peroxo / Transport

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