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Structure paper

TitleBiosynthesis of reveromycin derivatives by altering the regioselectivity of cytochrome P450revI.
Journal, issue, pagesChem Sci, Vol. 16, Page 13106-13114, Year 2025
Publish dateJan 20, 2025 (structure data deposition date)
AuthorsYong, Y.F. / Liu, S. / Sakai, K. / Fujiyama, K. / Takagi, H. / Futamura, Y. / Shimizu, T. / Osada, H. / Ong, E.B.B. / Takahashi, S.
External linksChem Sci / PubMed:40556721
MethodsX-ray diffraction
Resolution2.13 Å
Structure data

PDB-9ln5:
Crystal structure of P450revI A241L mutant in complex with reveromycin T
Method: X-RAY DIFFRACTION / Resolution: 2.13 Å

Chemicals

ChemComp-HEM:
PROTOPORPHYRIN IX CONTAINING FE

ChemComp-RRM:
(2E,4S,5S,6E,8E)-10-{(2R,3S,6S,8R,9S)-9-butyl-8-[(1E,3E)-4-carboxy-3-methylbuta-1,3-dien-1-yl]-3-methyl-1,7-dioxaspiro[5.5]undec-2-yl}-5-hydroxy-4,8-dimethyldeca-2,6,8-trienoic acid

ChemComp-CL:
Unknown entry

ChemComp-HOH:
WATER

Source
  • streptomyces sp. sn-593 (bacteria)
KeywordsOXIDOREDUCTASE / Cytochrome P450 / Heme / Reveromycin / Biosynthesis

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