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TitleMyoglobin-Catalyzed Azide Reduction Proceeds via an Anionic Metal Amide Intermediate.
Journal, issue, pagesJ. Am. Chem. Soc., Vol. 146, Page 1957-1966, Year 2024
Publish dateAug 24, 2023 (structure data deposition date)
AuthorsTinzl, M. / Diedrich, J.V. / Mittl, P.R.E. / Clemancey, M. / Reiher, M. / Proppe, J. / Latour, J.M. / Hilvert, D.
External linksJ. Am. Chem. Soc. / PubMed:38264790
MethodsX-ray diffraction
Resolution1.23 - 1.39 Å
Structure data

PDB-8qba:
Sperm whale myoblogin mutant H64V V68A in complex with glycine ethyl ester
Method: X-RAY DIFFRACTION / Resolution: 1.39 Å

PDB-8qbc:
Reactive amide intermediate in sperm whale myoglobin mutant H64V V68A
Method: X-RAY DIFFRACTION / Resolution: 1.23 Å

Chemicals

ChemComp-ACT:
ACETATE ION

ChemComp-HEM:
PROTOPORPHYRIN IX CONTAINING FE

ChemComp-GEE:
ethyl glycinate

ChemComp-HOH:
WATER

Source
  • physeter catodon (sperm whale)
KeywordsOXYGEN STORAGE / complex / amine complex

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