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Structure paper

TitleA Noble Metal Substitution Leads to B 12 Cofactor Mimicry by a Rhodibalamin.
Journal, issue, pagesBiochemistry, Vol. 63, Page 1955-1962, Year 2024
Publish dateMay 31, 2022 (structure data deposition date)
AuthorsRuetz, M. / Mascarenhas, R. / Widner, F. / Kieninger, C. / Koutmos, M. / Krautler, B. / Banerjee, R.
External linksBiochemistry / PubMed:39012171
MethodsX-ray diffraction
Resolution1.85 Å
Structure data

PDB-8d32:
Mycobacterium tuberculosis pduO-type ATP:cobalamin adenosyltransferase bound to 5-deoxyadenosylrhodibalamin and PPPi
Method: X-RAY DIFFRACTION / Resolution: 1.85 Å

Chemicals

ChemComp-SF0:
[5-(5,6-dimethyl-1H-benzimidazol-1-yl)-4-hydroxy-2-(hydroxymethyl)oxolan-3-yl 1-{3-[3,14,19-tris(2-amino-2-oxoethyl)-8,13,18-tris(3-amino-3-oxopropyl)-1,4,6,9,9,14,16,19-octamethyl-20,21,22,23-tetraazapentacyclo[15.2.1.1~2,5~.1~7,10~.1~12,15~]tricosa-5(23),6,10,12(21),15,17(20)-hexaen-4-yl-kappa~4~N~20~,N~21~,N~22~,N~23~]propanamido}propan-2-yl hydrogenato phosphate]rhodium (non-preferred name)

ChemComp-5AD:
5'-DEOXYADENOSINE

ChemComp-3PO:
TRIPHOSPHATE

ChemComp-MG:
Unknown entry

ChemComp-HOH:
WATER

Source
  • mycobacterium tuberculosis (bacteria)
KeywordsTRANSFERASE / chaperone / B12 trafficking / rhodium

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