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TitleReactivity of a fluorine-containing dirhodium tetracarboxylate compound with proteins
Journal, issue, pagesDalton Trans, Vol. 51, Year 2022
Publish dateMar 11, 2022 (structure data deposition date)
AuthorsLoreto, D. / Esposito, A. / Demitri, N. / Guaragna, A. / Merlino, A.
External linksDalton Trans / Search PubMed
MethodsX-ray diffraction
Resolution1.45 - 1.71 Å
Structure data

PDB-7z6d:
X-ray structure of the adduct obtained upon reaction of [Rh2(OCOCH3)(OCOCF3)3] with RNase A (1)
Method: X-RAY DIFFRACTION / Resolution: 1.45 Å

PDB-7z6g:
X-ray structure of the adduct obtained upon reaction of [Rh2(OCOCH3)(OCOCF3)3] with RNase A (2)
Method: X-RAY DIFFRACTION / Resolution: 1.71 Å

PDB-7z6j:
X-ray structure of the adduct obtained upon reaction of [Rh2(OCOCH3)(OCOCF3)3] with HEWL
Method: X-RAY DIFFRACTION / Resolution: 1.53 Å

Chemicals

ChemComp-ACT:
ACETATE ION

ChemComp-F3I:
(mi2-acetato-O, O')-hexaaquo-dirhodium (II)

ChemComp-RH:
Rhodium

ChemComp-HOH:
WATER

ChemComp-EPE:
4-(2-HYDROXYETHYL)-1-PIPERAZINE ETHANESULFONIC ACID / pH buffer*YM

ChemComp-NA:
Unknown entry

Source
  • bos taurus (domestic cattle)
  • gallus gallus (chicken)
KeywordsHYDROLASE / Protein metalation / dirhodium tetraacetate derivative / dimetallic paddlewheel complexes / model proteins

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