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Structure paper

TitleCatalytic Control of Spiroketal Formation in Rubromycin Polyketide Biosynthesis.
Journal, issue, pagesAngew. Chem. Int. Ed. Engl., Vol. 60, Page 26960-26970, Year 2021
Publish dateJun 11, 2021 (structure data deposition date)
AuthorsToplak, M. / Saleem-Batcha, R. / Piel, J. / Teufel, R.
External linksAngew. Chem. Int. Ed. Engl. / PubMed:34652045
MethodsX-ray diffraction
Resolution1.573 - 2.3 Å
Structure data

PDB-7ouc:
Crystal structure of the flavoprotein monooxygenase GrhO5 from griseorhodin A biosynthesis
Method: X-RAY DIFFRACTION / Resolution: 1.75 Å

PDB-7oud:
Crystal structure of a ternary complex of the flavoprotein monooxygenase GrhO5 with FAD and collinone
Method: X-RAY DIFFRACTION / Resolution: 2.3 Å

PDB-7ouj:
Crystal structure of the flavoprotein monooxygenase RubL from rubromycin biosynthesis
Method: X-RAY DIFFRACTION / Resolution: 1.573 Å

Chemicals

ChemComp-FAD:
FLAVIN-ADENINE DINUCLEOTIDE / FAD*YM

ChemComp-HOH:
WATER

ChemComp-1J0:
Collinone

ChemComp-CL:
Unknown entry

ChemComp-1JW:
(2S)-hexane-1,2,6-triol

ChemComp-HYP:
4-HYDROXYPROLINE

ChemComp-GOL:
GLYCEROL

Source
  • streptomyces sp. jp95 (bacteria)
  • streptomyces collinus (bacteria)
KeywordsFLAVOPROTEIN / monooxygenase / griseorhodin A biosynthesis / rubromycin biosynthesis

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