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TitleReactivity and Selectivity of Iminium Organocatalysis Improved by a Protein Host.
Journal, issue, pagesAngew. Chem. Int. Ed. Engl., Vol. 57, Page 12478-12482, Year 2018
Publish dateMay 4, 2018 (structure data deposition date)
AuthorsNodling, A.R. / Swiderek, K. / Castillo, R. / Hall, J.W. / Angelastro, A. / Morrill, L.C. / Jin, Y. / Tsai, Y.H. / Moliner, V. / Luk, L.Y.P.
External linksAngew. Chem. Int. Ed. Engl. / PubMed:30027571
MethodsX-ray diffraction
Resolution1.08 Å
Structure data

PDB-6gh7:
WILDTYPE CORE-STREPTAVIDIN WITH a conjugated BIOTINYLATED PYRROLIDINE
Method: X-RAY DIFFRACTION / Resolution: 1.08 Å

Chemicals

ChemComp-EYW:
5-[(3~{a}~{S},4~{S},6~{a}~{R})-2-oxidanylidene-1,3,3~{a},4,6,6~{a}-hexahydrothieno[3,4-d]imidazol-4-yl]-~{N}-[(3~{R})-pyrrolidin-3-yl]pentanamide

ChemComp-HOH:
WATER

Source
  • streptomyces avidinii (bacteria)
KeywordsBIOTIN-BINDING PROTEIN / Organocatalysis / Supramolecular chemistry / secondary amine / artificial enzyme

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