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Structure paper

TitlePeroxidase versus Peroxygenase Activity: Substrate Substituent Effects as Modulators of Enzyme Function in the Multifunctional Catalytic Globin Dehaloperoxidase.
Journal, issue, pagesBiochemistry, Vol. 57, Page 4455-4468, Year 2018
Publish dateFeb 21, 2018 (structure data deposition date)
AuthorsMcGuire, A.H. / Carey, L.M. / de Serrano, V. / Dali, S. / Ghiladi, R.A.
External linksBiochemistry / PubMed:29949340
MethodsX-ray diffraction
Resolution1.37 - 1.7 Å
Structure data

PDB-6ch5:
Dehaloperoxidase B in complex with substrate 4-Nitroguaiacol
Method: X-RAY DIFFRACTION / Resolution: 1.65 Å

PDB-6ch6:
Dehaloperoxidase B in complex with substrate 2,4-dimethoxyphenol
Method: X-RAY DIFFRACTION / Resolution: 1.7 Å

PDB-6cke:
Dehaloperoxidase B in complex with 4-Br-guaiacol
Method: X-RAY DIFFRACTION / Resolution: 1.37 Å

PDB-6co5:
Dehaloperoxidase B in complex with 6-Br-ortho-guaiacol
Method: X-RAY DIFFRACTION / Resolution: 1.686 Å

PDB-6cre:
Dehaloperoxidase B in complex with 5-Br-ortho-guaiacol
Method: X-RAY DIFFRACTION / Resolution: 1.58 Å

Chemicals

ChemComp-HEM:
PROTOPORPHYRIN IX CONTAINING FE

ChemComp-SO4:
SULFATE ION

ChemComp-GOL:
GLYCEROL

ChemComp-F0M:
2-methoxy-4-nitrophenol

ChemComp-PEG:
DI(HYDROXYETHYL)ETHER

ChemComp-HOH:
WATER

ChemComp-F0J:
2,4-dimethoxyphenol

ChemComp-3Z7:
4-bromo-2-methoxyphenol

ChemComp-F81:
2-bromo-6-methoxyphenol

ChemComp-F9G:
5-bromo-2-methoxyphenol

Source
  • amphitrite ornata (invertebrata)
KeywordsOXIDOREDUCTASE / METAL BINDING PROTEIN / peroxidase / peroxygenase / substrate

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