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TitleFormation of a Novel Macrocyclic Alkaloid from the Unnatural Farnesyl Diphosphate Analogue Anilinogeranyl Diphosphate by 5-Epi-Aristolochene Synthase.
Journal, issue, pagesAcs Chem. Biol., Vol. 10, Page 1729-1736, Year 2015
Publish dateOct 24, 2014 (structure data deposition date)
AuthorsRising, K.A. / Crenshaw, C.M. / Koo, H.J. / Subramanian, T. / Chehade, K.A. / Starks, C. / Allen, K.D. / Andres, D.A. / Spielmann, H.P. / Noel, J.P. / Chappell, J.
External linksAcs Chem. Biol. / PubMed:25897591
MethodsX-ray diffraction
Resolution2.47 Å
Structure data

PDB-4rnq:
Crystal structure of tobacco 5-epi-aristolochene synthase (TEAS) with anilinogeranyl diphosphate (AGPP) and geraniline
Method: X-RAY DIFFRACTION / Resolution: 2.47 Å

Chemicals

ChemComp-MG:
Unknown entry

ChemComp-A4S:
(2E,6E)-3,7-dimethyl-8-(phenylamino)octa-2,6-dien-1-yl trihydrogen diphosphate

ChemComp-1GA:
Geraniline

ChemComp-DPO:
DIPHOSPHATE

ChemComp-ACT:
ACETATE ION

ChemComp-HOH:
WATER

Source
  • nicotiana tabacum (common tobacco)
KeywordsLYASE / TEAS / 5-epi-aristolochene synthase / anilinogeranyl diphosphate (AGPP) / geraniline / terpene synthase

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