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TitleUnexpected reactivity of 2-fluorolinalyl diphosphate in the active site of crystalline 2-methylisoborneol synthase.
Journal, issue, pagesBiochemistry, Vol. 52, Page 5247-5255, Year 2013
Publish dateJun 19, 2013 (structure data deposition date)
AuthorsKoksal, M. / Chou, W.K. / Cane, D.E. / Christianson, D.W.
External linksBiochemistry / PubMed:23844678
MethodsX-ray diffraction
Resolution1.849 - 2.001 Å
Structure data

PDB-4la5:
Crystal structure of 2-methylisoborneol synthase from Streptomyces coelicolor A3(2)
Method: X-RAY DIFFRACTION / Resolution: 1.849 Å

PDB-4la6:
Crystal structure of 2-methylisoborneol synthase from Streptomyces coelicolor A3(2) in complex with Mg2+ and 2-fluoroneryl diphosphate
Method: X-RAY DIFFRACTION / Resolution: 2.001 Å

Chemicals

ChemComp-HOH:
WATER

ChemComp-MG:
Unknown entry

ChemComp-LA6:
(2E)-2-fluoro-3,7-dimethylocta-2,6-dien-1-yl trihydrogen diphosphate

Source
  • streptomyces coelicolor (bacteria)
KeywordsLYASE / terpenoid biosynthesis / biosynthesis / isoprenoid synthase fold

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