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TitleSnapshot of a Key Intermediate in Enzymatic Thiamin Catalysis: Crystal Structure of the Alpha-Carbanion of (Alpha,Beta-Dihydroxyethyl)-Thiamin Diphosphate in the Active Site of Transketolase from Saccharomyces Cerevisiae.
Journal, issue, pagesProc. Natl. Acad. Sci. USA, Vol. 99, Page 591-, Year 2002
Publish dateNov 9, 2001 (structure data deposition date)
AuthorsFiedler, E. / Thorell, S. / Sandalova, T. / Golbik, R. / Koenig, S. / Schneider, G.
External linksProc. Natl. Acad. Sci. USA / PubMed:11773632
MethodsX-ray diffraction
Resolution1.86 Å
Structure data

PDB-1gpu:
Transketolase complex with reaction intermediate
Method: X-RAY DIFFRACTION / Resolution: 1.86 Å

Chemicals

ChemComp-CA:
Unknown entry

ChemComp-THD:
2-[3-[(4-AMINO-2-METHYL-5-PYRIMIDINYL)METHYL]-2-(1,2-DIHYDROXYETHYL)-4-METHYL-1,3-THIAZOL-3-IUM-5-YL]ETHYL TRIHYDROGEN

ChemComp-HOH:
WATER

Source
  • saccharomyces cerevisiae (brewer's yeast)
KeywordsTRANSFERASE / TRANSFERASE(KETONE RESIDUES)

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