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Structure paper

TitleIntramolecular C-C Bond Formation Links Anthraquinone and Enediyne Scaffolds in Tiancimycin Biosynthesis.
Journal, issue, pagesJ. Am. Chem. Soc., Vol. 144, Page 20452-20462, Year 2022
Publish dateAug 10, 2022 (structure data deposition date)
AuthorsGui, C. / Kalkreuter, E. / Liu, Y.C. / Adhikari, A. / Teijaro, C.N. / Yang, D. / Chang, C. / Shen, B.
External linksJ. Am. Chem. Soc. / PubMed:36279548
MethodsX-ray diffraction
Resolution1.14 - 2.03 Å
Structure data

PDB-8e18:
Crystal structure of apo TnmK1
Method: X-RAY DIFFRACTION / Resolution: 1.14 Å

PDB-8e19:
Crystal structure of TnmK1 complexed with TNM H
Method: X-RAY DIFFRACTION / Resolution: 2.03 Å

Chemicals

ChemComp-EPE:
4-(2-HYDROXYETHYL)-1-PIPERAZINE ETHANESULFONIC ACID / pH buffer*YM

ChemComp-HOH:
WATER

ChemComp-U8L:
(1R,8S,13S)-8-[(4-hydroxy-9,10-dioxo-9,10-dihydroanthracen-1-yl)amino]-12-methoxy-10-methylbicyclo[7.3.1]trideca-9,11-diene-2,6-diyne-13-carbaldehyde

ChemComp-SIN:
SUCCINIC ACID

Source
  • streptomyces sp. cb03234 (bacteria)
KeywordsHYDROLASE / biosynthesis

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