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TitleDirected Evolution Enables Dynamic Control of Transient Intermediates for Anti-Markovnikov Wacker-Tsuji-Type Oxidation of Unactivated Alkenes
Journal, issue, pagesChemrxiv, Year 2024
Publish dateAug 2, 2023 (structure data deposition date)
AuthorsKlaus, C. / Soler, J. / Kubik, G. / Gumulya, Y. / Hui, Y. / Watkins-Dulaney, E.J. / Heitland, ML. / Sommer, M. / Klein, A. / Kowal, J.L. ...Klaus, C. / Soler, J. / Kubik, G. / Gumulya, Y. / Hui, Y. / Watkins-Dulaney, E.J. / Heitland, ML. / Sommer, M. / Klein, A. / Kowal, J.L. / Niemann, H.H. / Arnold, F.H. / Garcia-Borras.M. / Hammer, S.C.
External linksChemrxiv / Search PubMed
MethodsX-ray diffraction
Resolution3.43 Å
Structure data

PDB-8q2f:
Cytochrome P450 BM3 aMOx-A heme domain
Method: X-RAY DIFFRACTION / Resolution: 3.43 Å

Chemicals

ChemComp-HEM:
PROTOPORPHYRIN IX CONTAINING FE

ChemComp-GOL:
GLYCEROL

ChemComp-ACT:
ACETATE ION

ChemComp-SO4:
SULFATE ION

Source
  • priestia megaterium (bacteria)
KeywordsOXIDOREDUCTASE / Cytochrome P450 monooxygenase / Anti-Markovnikov oxygenase

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