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Structure paper

TitleP450-Mediated Dual Cyclization Mechanisms for Pyrroloindoline Unit Formation in Bispyrrolidinoindoline Diketopiperazine Alkaloid Biosynthesis.
Journal, issue, pagesJ. Am. Chem. Soc., Vol. 147, Page 45199-45209, Year 2025
Publish dateJul 24, 2025 (structure data deposition date)
AuthorsDu, Y. / Wei, G. / Zhou, T.P. / Dai, Y. / Tian, W. / Tang, M. / Deng, Z. / Wang, B. / Qu, X.
External linksJ. Am. Chem. Soc. / PubMed:41326270
MethodsX-ray diffraction
Resolution2.48 - 2.5 Å
Structure data

PDB-9w0a:
Wild-type P450 enzyme-TtpB1
Method: X-RAY DIFFRACTION / Resolution: 2.48 Å

PDB-9w5t:
The complex structure of wild-type P450 enzyme with cww
Method: X-RAY DIFFRACTION / Resolution: 2.5 Å

Chemicals

PDB-1euf:
BOVINE DUODENASE(NEW SERINE PROTEASE), CRYSTAL STRUCTURE

ChemComp-HEM:
PROTOPORPHYRIN IX CONTAINING FE

ChemComp-HOH:
WATER

ChemComp-UYM:
(3S,6S)-3,6-bis[(1H-indol-3-yl)methyl]piperazine-2,5-dione

ChemComp-NA:
Unknown entry

Source
  • escherichia coli (E. coli)
KeywordsBIOSYNTHETIC PROTEIN / Complex / Cytochrome P450 enzyme / Dimerase / Complex.

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