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TitleDihydroxy Terpene Synthase: Spatiotemporally Precise Manipulation of Water-Mediated Dihydroxylation via Stepwise Quenching of Carbocations.
Journal, issue, pagesJ. Am. Chem. Soc., Vol. 147, Page 45822-45831, Year 2025
Publish dateNov 29, 2023 (structure data deposition date)
AuthorsHuang, Z.Y. / Xu, K. / Li, W.L. / Li, C.X. / Pan, J. / Wu, R. / Xu, J.H.
External linksJ. Am. Chem. Soc. / PubMed:41273278
MethodsX-ray diffraction
Resolution1.68 - 1.99 Å
Structure data

PDB-8x9c:
Class I terpene synthase: eudesmanediol synthase (apo-PeTS3)
Method: X-RAY DIFFRACTION / Resolution: 1.68 Å

PDB-9kqw:
eudesmanediol synthase complexed with Mg2+,PPi and BTAC(PeTS3 complex)
Method: X-RAY DIFFRACTION / Resolution: 1.99 Å

Chemicals

ChemComp-HOH:
WATER

ChemComp-POP:
PYROPHOSPHATE 2-

ChemComp-BTM:
N-benzyl-N,N-diethylethanaminium

ChemComp-MG:
Unknown entry

Source
  • penicillium expansum (fungus)
KeywordsLIGASE / sesquiterpene / terpene synthase / LYASE / eudesmanediol / PPi / BTAC

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