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TitleUnusual O-H Activation-Initiated C-C Bond Cleavage Reaction by a Nonheme Fe Enzyme in Antifungal Nucleoside Biosynthesis.
Journal, issue, pagesJ. Am. Chem. Soc., Vol. 147, Page 30163-30177, Year 2025
Publish dateNov 25, 2024 (structure data deposition date)
AuthorsDu, Y. / Dong, J. / Draelos, M.M. / Collazo-Perez, L.N. / Majer, S.H. / Boal, A.K. / Yokoyama, K.
External linksJ. Am. Chem. Soc. / PubMed:40787846
MethodsX-ray diffraction
Resolution1.44 - 1.48 Å
Structure data

PDB-9ei6:
PasI from Photorhabdus asymbiotica bound to Fe(II) and alpha-ketoglutarate
Method: X-RAY DIFFRACTION / Resolution: 1.44 Å

PDB-9ei7:
PasI from Photorhabdus asymbiotica bound to vanadyl, succinate, and 5-amino-6-hydroxy-octanosyl acid 2-phosphate
Method: X-RAY DIFFRACTION / Resolution: 1.48 Å

Chemicals

ChemComp-AKG:
2-OXOGLUTARIC ACID

ChemComp-SO4:
SULFATE ION

ChemComp-GOL:
GLYCEROL

ChemComp-PEG:
DI(HYDROXYETHYL)ETHER

ChemComp-FE:
Unknown entry

ChemComp-HOH:
WATER

PDB-1bik:
X-RAY STRUCTURE OF BIKUNIN FROM THE HUMAN INTER-ALPHA-INHIBITOR COMPLEX

ChemComp-SIN:
SUCCINIC ACID

ChemComp-CL:
Unknown entry

ChemComp-V:
VANADIUM ION

Source
  • photorhabdus asymbiotica (bacteria)
KeywordsOXIDOREDUCTASE / iron / polyoxin / biosynthesis / nucleotide / high-carbon sugar / vanadyl / oxygen

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