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TitleAn Alternative Mechanism for C-C Desaturation Underscores a Dual-Controlled Mechanism for the Fate of Radical Intermediate in Iron(II)- and 2-(Oxo)glutarate-Dependent Oxygenase DfmD.
Journal, issue, pagesJ. Am. Chem. Soc., Vol. 147, Page 20442-20455, Year 2025
Publish dateAug 2, 2024 (structure data deposition date)
AuthorsZhang, X. / Wang, L. / Liu, J. / Chen, T.Y. / Yan, S. / Chang, W.C. / Shaik, S. / Zhou, J. / Wang, B.
External linksJ. Am. Chem. Soc. / PubMed:40480968
MethodsX-ray diffraction
Resolution2.85 Å
Structure data

PDB-9j0j:
The crystal structure of Fe/2OG-dependent oxygenase DfmD
Method: X-RAY DIFFRACTION / Resolution: 2.85 Å

Chemicals

ChemComp-FE:
Unknown entry

ChemComp-ZN:
Unknown entry

ChemComp-GOL:
GLYCEROL

ChemComp-HOH:
WATER

Source
  • streptomyces lavendulae (bacteria)
KeywordsOXIDOREDUCTASE / oxygenase / DfmD

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