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TitleBiocatalytic strategy for the construction of sp 3 -rich polycyclic compounds from directed evolution and computational modelling.
Journal, issue, pagesNat. Chem., Vol. 16, Page 817-826, Year 2024
Publish dateOct 24, 2021 (structure data deposition date)
AuthorsVargas, D.A. / Ren, X. / Sengupta, A. / Zhu, L. / Roy, S. / Garcia-Borras, M. / Houk, K.N. / Fasan, R.
External linksNat. Chem. / PubMed:38351380
MethodsX-ray diffraction
Resolution1.15 - 2 Å
Structure data

PDB-7slh:
Engineered sperm whale myoglobin-based carbene transferase MbBTIC-C3
Method: X-RAY DIFFRACTION / Resolution: 1.15 Å

PDB-7sli:
Engineered sperm whale myoglobin-based carbene transferase MbBTIC-C2
Method: X-RAY DIFFRACTION / Resolution: 2 Å

Chemicals

ChemComp-HEM:
PROTOPORPHYRIN IX CONTAINING FE

ChemComp-SO4:
SULFATE ION

ChemComp-HOH:
WATER

Source
  • physeter catodon (sperm whale)
KeywordsOXYGEN STORAGE / METALLOPROTEIN / MYOGLOBIN / HEME / TRANSFERASE / OXYGEN TRANSPORT

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