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TitleEnabling Peroxygenase Activity in Cytochrome P450 Monooxygenases by Engineering Hydrogen Peroxide Tunnels.
Journal, issue, pagesJ. Am. Chem. Soc., Vol. 145, Page 5506-5511, Year 2023
Publish dateNov 14, 2022 (structure data deposition date)
AuthorsZhao, P. / Kong, F. / Jiang, Y. / Qin, X. / Tian, X. / Cong, Z.
External linksJ. Am. Chem. Soc. / PubMed:36790023
MethodsX-ray diffraction
Resolution1.72 - 2.06 Å
Structure data

PDB-8hgc:
Crystal structure of the CYP199A4 mutant F182T in complex with 4-methoxybenzoic acid
Method: X-RAY DIFFRACTION / Resolution: 1.72 Å

PDB-8hgt:
Crystal structure of the CYP153A mutant V456A from Marinobacter aquaeolei
Method: X-RAY DIFFRACTION / Resolution: 2.06 Å

Chemicals

ChemComp-HEM:
PROTOPORPHYRIN IX CONTAINING FE

ChemComp-ANN:
4-METHOXYBENZOIC ACID

ChemComp-GOL:
GLYCEROL

ChemComp-ACT:
ACETATE ION

ChemComp-HOH:
WATER

Source
  • rhodopseudomonas palustris haa2 (phototrophic)
  • marinobacter nauticus (bacteria)
KeywordsOXIDOREDUCTASE / CYP199A4 / Complex / CYP153A

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