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TitleAn Iron(IV)-Oxo Intermediate Initiating l-Arginine Oxidation but Not Ethylene Production by the 2-Oxoglutarate-Dependent Oxygenase, Ethylene-Forming Enzyme.
Journal, issue, pagesJ. Am. Chem. Soc., Vol. 143, Page 2293-2303, Year 2021
Publish dateFeb 1, 2020 (structure data deposition date)
AuthorsCopeland, R.A. / Davis, K.M. / Shoda, T.K.C. / Blaesi, E.J. / Boal, A.K. / Krebs, C. / Bollinger Jr., J.M.
External linksJ. Am. Chem. Soc. / PubMed:33522811
MethodsX-ray diffraction
Resolution1.83 - 1.97 Å
Structure data

PDB-6vp4:
Ethylene forming enzyme (EFE) in complex with Fe(II), L-arginine, and 2OG
Method: X-RAY DIFFRACTION / Resolution: 1.83 Å

PDB-6vp5:
Ethylene forming enzyme (EFE) D191E variant in complex with Fe(II), L-arginine, and 2OG
Method: X-RAY DIFFRACTION / Resolution: 1.97 Å

Chemicals

ChemComp-FE:
Unknown entry

ChemComp-AKG:
2-OXOGLUTARIC ACID

ChemComp-ARG:
ARGININE

ChemComp-B3P:
2-[3-(2-HYDROXY-1,1-DIHYDROXYMETHYL-ETHYLAMINO)-PROPYLAMINO]-2-HYDROXYMETHYL-PROPANE-1,3-DIOL / pH buffer*YM

ChemComp-HOH:
WATER

Source
  • pseudomonas savastanoi pv. phaseolicola (bacteria)
KeywordsOXIDOREDUCTASE / 2-oxo-glutarate / iron / reactant complex

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