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Structure paper

TitleA Combined Spectroscopic and Protein Crystallography Study Reveals Protein Interactions of Rh I (NHC) Complexes at the Molecular Level.
Journal, issue, pagesInorg. Chem., Vol. 59, Page 17191-17199, Year 2020
Publish dateApr 29, 2020 (structure data deposition date)
AuthorsDaubit, I.M. / Sullivan, M.P. / John, M. / Goldstone, D.C. / Hartinger, C.G. / Metzler-Nolte, N.
External linksInorg. Chem. / PubMed:33180473
MethodsX-ray diffraction
Resolution1.35 - 1.55 Å
Structure data

PDB-6wrl:
The interaction of chlorido(1,5-cyclooctadiene)([4-(2-((tert-butoxycarbonyl)amino)-3-methoxy-3-oxopropyl)-1,3-dimethyl-1H-imidazol-3-ide])rhodium(I) with HEWL after 1 week
Method: X-RAY DIFFRACTION / Resolution: 1.35 Å

PDB-6wrm:
The interaction of chlorido(1,5-cyclooctadiene)([4-(2-((tert-butoxycarbonyl)amino)-3-methoxy-3-oxopropyl)-1,3-dimethyl-1H-imidazol-3-ide])rhodium(I) with HEWL after 1 month
Method: X-RAY DIFFRACTION / Resolution: 1.55 Å

Chemicals

ChemComp-NA:
Unknown entry

ChemComp-ACT:
ACETATE ION

ChemComp-RH:
Rhodium

ChemComp-HOH:
WATER

ChemComp-CL:
Unknown entry

ChemComp-U8G:
(4-{2-[(tert-butoxycarbonyl)amino]-3-methoxy-3-oxopropyl}-1,3-dimethyl-2,3-dihydro-1H-imidazol-2-yl)rhodium

Source
  • gallus gallus (chicken)
KeywordsHYDROLASE / Metal-based / Anticancer / Rhodium / NHC / Carbene / HEWL / Hen egg White Lysozyme / Lysozyme / Metallodrug / Imidazole

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