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TitleCaught in the H inact : Crystal Structure and Spectroscopy Reveal a Sulfur Bound to the Active Site of an O 2 -stable State of [FeFe] Hydrogenase.
Journal, issue, pagesAngew. Chem. Int. Ed. Engl., Vol. 59, Page 16786-16794, Year 2020
Publish dateAug 2, 2019 (structure data deposition date)
AuthorsRodriguez-Macia, P. / Galle, L.M. / Bjornsson, R. / Lorent, C. / Zebger, I. / Yoda, Y. / Cramer, S.P. / DeBeer, S. / Span, I. / Birrell, J.A.
External linksAngew. Chem. Int. Ed. Engl. / PubMed:32488975
MethodsX-ray diffraction
Resolution1.65 Å
Structure data

PDB-6sg2:
FeFe Hydrogenase from Desulfovibrio desulfuricans in Hinact state
Method: X-RAY DIFFRACTION / Resolution: 1.65 Å

Chemicals

ChemComp-SF4:
IRON/SULFUR CLUSTER

ChemComp-LFH:
dicarbonyl[bis(cyanide-kappaC)]-mu-(iminodimethanethiolatato-1kappaS:2kappaS)-mu-(oxomethylidene)diiron(2+) sulphide

ChemComp-HOH:
WATER

Source
  • desulfovibrio desulfuricans (bacteria)
KeywordsOXIDOREDUCTASE / Hydrogenase / iron-sulfur protein / Hinact / Desulfovibrio desulfuricans

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