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-Structure paper
タイトル | Precise Control Over Kinetics of Molecular Assembly: Production of Particles with Tunable Sizes and Crystalline Forms. |
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ジャーナル・号・ページ | Angew Chem Int Ed Engl, Vol. 59, Issue 35, Page 15141-15146, Year 2020 |
掲載日 | 2020年8月24日 |
![]() | Qingrui Fan / Linhai Li / Han Xue / Heng Zhou / Lishan Zhao / Jie Liu / Junqiang Mao / Shuwang Wu / Shizhong Zhang / Chenyang Wu / Xueming Li / Xin Zhou / Jianjun Wang / ![]() |
PubMed 要旨 | It has been long-pursued but remains a challenge to precisely manipulate the molecular assembly process to obtain desired functional structures. Reported here is the control over the assembly of ...It has been long-pursued but remains a challenge to precisely manipulate the molecular assembly process to obtain desired functional structures. Reported here is the control over the assembly of solute molecules, by a programmed recrystallization of solvent crystal grains, to form micro/nanoparticles with tunable sizes and crystalline forms. A quantitative correlation between the protocol of recrystallization temperature and the assembly kinetics results in precise control over the size of assembled particles, ranging from single-atom catalysts, pure drug nanoparticles, to sub-millimeter organic-semiconductor single crystals. The extensive regulation of the assembly rates leads to the unique and powerful capability of tuning the stacking of molecules, involving the formation of single crystals of notoriously crystallization-resistant molecules and amorphous structures of molecules with a very high propensity to crystallize, which endows it with wide-ranging applications. |
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手法 | EM (電子線結晶学) |
解像度 | 1.05 - 1.2 Å |
構造データ | EMDB-30288, PDB-7c4u: EMDB-30289, PDB-7c4v: |
化合物 | ![]() ChemComp-CL: ![]() ChemComp-HOH: |
由来 |
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![]() | ANTIBIOTIC / MicroED / Vancomycin / superbacteria |