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TitleOrigin of high stereocontrol in olefin cyclopropanation catalyzed by an engineered carbene transferase.
Journal, issue, pagesAcs Catalysis, Vol. 9, Page 1514-1524, Year 2019
Publish dateAug 21, 2018 (structure data deposition date)
AuthorsTinoco, A. / Wei, Y. / Bacik, J.P. / Carminati, D.M. / Moore, E.J. / Ando, N. / Zhang, Y. / Fasan, R.
External linksAcs Catalysis / PubMed:31134138
MethodsX-ray diffraction
Resolution1.1 Å
Structure data

PDB-6m8f:
Engineered sperm whale myoglobin-based carbene transferase
Method: X-RAY DIFFRACTION / Resolution: 1.1 Å

Chemicals

ChemComp-SO4:
SULFATE ION

ChemComp-HEM:
PROTOPORPHYRIN IX CONTAINING FE

ChemComp-HOH:
WATER

Source
  • physeter catodon (sperm whale)
KeywordsTRANSFERASE / Metalloprotein / myoglobin / carbene transferase / cyclopropanation / heme

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