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TitleEnzyme repurposing of a hydrolase as an emergent peroxidase upon metal binding.
Journal, issue, pagesChem Sci, Vol. 6, Page 4060-4065, Year 2015
Publish dateMay 31, 2014 (structure data deposition date)
AuthorsFujieda, N. / Schatti, J. / Stuttfeld, E. / Ohkubo, K. / Maier, T. / Fukuzumi, S. / Ward, T.R.
External linksChem Sci / PubMed:29218172
MethodsX-ray diffraction
Resolution1.39 - 1.81 Å
Structure data

PDB-4tm7:
Crystal structure of 6-phosphogluconolactonase from Mycobacterium smegmatis N131D mutant soaked with CuSO4
Method: X-RAY DIFFRACTION / Resolution: 1.39 Å

PDB-4tm8:
Crystal structure of 6-phosphogluconolactonase from Mycobacterium smegmatis N131D mutant
Method: X-RAY DIFFRACTION / Resolution: 1.81 Å

Chemicals

ChemComp-EDO:
1,2-ETHANEDIOL

ChemComp-SO4:
SULFATE ION

ChemComp-CU1:
COPPER (I) ION

ChemComp-CU:
COPPER (II) ION

ChemComp-CL:
Unknown entry

ChemComp-HOH:
WATER

Source
  • mycobacterium smegmatis (bacteria)
KeywordsHYDROLASE / Rossmann fold

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