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TitleDirect Hydroxylation of Benzene to Phenol by Cytochrome P450BM3 Triggered by Amino Acid Derivatives.
Journal, issue, pagesAngew. Chem. Int. Ed. Engl., Vol. 56, Page 10324-10329, Year 2017
Publish dateMar 10, 2017 (structure data deposition date)
AuthorsShoji, O. / Yanagisawa, S. / Stanfield, J.K. / Suzuki, K. / Cong, Z. / Sugimoto, H. / Shiro, Y. / Watanabe, Y.
External linksAngew. Chem. Int. Ed. Engl. / PubMed:28544674
MethodsX-ray diffraction
Resolution2.2 Å
Structure data

PDB-5xa3:
Crystal Structure of P450BM3 with Benzyloxycarbonyl-L-prolyl-L-phenylalanine
Method: X-RAY DIFFRACTION / Resolution: 2.2 Å

Chemicals

ChemComp-HEM:
PROTOPORPHYRIN IX CONTAINING FE

ChemComp-DMS:
DIMETHYL SULFOXIDE / DMSO, precipitant*YM

ChemComp-PRO:
PROLINE

ChemComp-PHE:
PHENYLALANINE

ChemComp-PHQ:
benzyl chlorocarbonate

ChemComp-HOH:
WATER

Source
  • bacillus megaterium (strain atcc 14581 / dsm 32 / jcm 2506 / nbrc 15308 / ncimb 9376 / nctc 10342 / vkm b-512) (bacteria)
KeywordsOXIDOREDUCTASE / Cytochrome P450

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