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TitleUnusual mode of protein binding by a cytotoxic pi-arene ruthenium(ii) piano-stool compound containing an O,S-chelating ligand.
Journal, issue, pagesDalton Trans, Vol. 45, Page 12283-12287, Year 2016
Publish dateApr 27, 2016 (structure data deposition date)
AuthorsHildebrandt, J. / Gorls, H. / Hafner, N. / Ferraro, G. / Durst, M. / Runnebaum, I.B. / Weigand, W. / Merlino, A.
External linksDalton Trans / PubMed:27427335
MethodsX-ray diffraction
Resolution1.79 Å
Structure data

PDB-5jlg:
The X-ray structure of the adduct formed in the reaction between bovine pancreatic ribonuclease and compound I, a piano-stool organometallic Ru(II) arene compound containing an O,S-chelating ligand
Method: X-RAY DIFFRACTION / Resolution: 1.79 Å

Chemicals

ChemComp-RU:
RUTHENIUM ION

ChemComp-6L6:
methyl (2Z)-3-hydroxy-3-(3-hydroxyphenyl)prop-2-ene(dithioate)

ChemComp-DMS:
DIMETHYL SULFOXIDE / DMSO, precipitant*YM

ChemComp-HOH:
WATER

Source
  • bos taurus (domestic cattle)
KeywordsHYDROLASE / ruthenated protein / protein-Ru compound adducts / piano-stool organometallic Ru(II) arene compounds

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